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学科主题: 公共卫生
题名:
Selective oxidation of benzylic or allylic hydroxyl group of sec-1,2-diols
作者: Peng, K; Chen, FX; She, XG; Yang, CH; Cui, YX; Pan, XF
关键词: selective oxidation ; DDQ ; ultrasound wave ; vicinal position
刊名: TETRAHEDRON LETTERS
发表日期: 2005-02-14
DOI: 10.1016/j.tetlet.2004.12.073
卷: 46, 期:7, 页:1217-1220
收录类别: SCI ; IC ; CCR
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
关键词[WOS]: CARBONYL-COMPOUNDS ; KETONES ; PURITY ; DIOLS
英文摘要:

A mild and efficient method to selectively oxidize chiral sec-1,2-diols has been developed, which demonstrates that 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) can selectively oxidize benzylic or allylic hydroxyl group of sec-1,2-diols under ultrasound wave promotion. The configuration of the adjacent chiral center is retained. (C) 2004 Elsevier Ltd. All rights reserved.

语种: 英语
WOS记录号: WOS:000226846800039
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/123612
Appears in Collections:北京大学医药卫生分析中心_期刊论文

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作者单位: 1.Lanzhou Univ, Dept Chem, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
3.Peking Univ, Med Healthy Anal Ctr, Beijing 100083, Peoples R China

Recommended Citation:
Peng, K,Chen, FX,She, XG,et al. Selective oxidation of benzylic or allylic hydroxyl group of sec-1,2-diols[J]. TETRAHEDRON LETTERS,2005,46(7):1217-1220.
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