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Bromodimethylsulfonium bromide-silver triflate: A new powerful promoter system for the activation of thioglycosides
Xiong, De-Cai; Zhang, Li-He; Ye, Xin-Shan
关键词Bromodimethylsufonium Bromide (Bdms) Glycosylation Oligosaccharides Promoter Thioglycosides
刊名ADVANCED SYNTHESIS & CATALYSIS
2008-08-01
DOI10.1002/adsc.200800190
350期:11-12页:1696-1700
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Applied ; Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]POT OLIGOSACCHARIDE SYNTHESIS ; GLYCOSIDIC LINKAGES ; MEDIATED FORMATION ; O-GLYCOSIDES ; GLYCOSYLATION ; DONORS ; ANHYDRIDE ; STRATEGY ; MILD
英文摘要

Bromodimethylsulfonium bromide (BDMS) in combination with silver triflate provides a very efficient thiophilic promoter system, capable of activating both "disarmed" and "armed" thioglycosides for glycosidic bond formation. The usefulness of this new promoter is illustrated by a successful reactivity-based one-pot oligosaccharide assembly.

语种英语
WOS记录号WOS:000258503600006
项目编号973 ; 863
资助机构National Natural Science Foundation of China ; Ministry of Science and Technology of China
引用统计
被引频次:20[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/50531
专题北京大学药学院
北京大学药学院_天然药物与仿生药物国家重点实验室
北京大学药学院_药物化学系
作者单位Peking Univ, State Key Lab Nat & Biomimet Drugs, Sch Pharmaceut Sci, Beijing 100083, Peoples R China
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Xiong, De-Cai,Zhang, Li-He,Ye, Xin-Shan. Bromodimethylsulfonium bromide-silver triflate: A new powerful promoter system for the activation of thioglycosides[J]. ADVANCED SYNTHESIS & CATALYSIS,2008,350(11-12):1696-1700.
APA Xiong, De-Cai,Zhang, Li-He,&Ye, Xin-Shan.(2008).Bromodimethylsulfonium bromide-silver triflate: A new powerful promoter system for the activation of thioglycosides.ADVANCED SYNTHESIS & CATALYSIS,350(11-12),1696-1700.
MLA Xiong, De-Cai,et al."Bromodimethylsulfonium bromide-silver triflate: A new powerful promoter system for the activation of thioglycosides".ADVANCED SYNTHESIS & CATALYSIS 350.11-12(2008):1696-1700.
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