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学科主题: 药学
题名:
Bromodimethylsulfonium bromide-silver triflate: A new powerful promoter system for the activation of thioglycosides
作者: Xiong, De-Cai; Zhang, Li-He; Ye, Xin-Shan
关键词: bromodimethylsufonium bromide (BDMS) ; glycosylation ; oligosaccharides ; promoter ; thioglycosides
刊名: ADVANCED SYNTHESIS & CATALYSIS
发表日期: 2008-08-01
DOI: 10.1002/adsc.200800190
卷: 350, 期:11-12, 页:1696-1700
收录类别: SCI ; IC ; CCR
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Applied ; Chemistry, Organic
研究领域[WOS]: Chemistry
关键词[WOS]: POT OLIGOSACCHARIDE SYNTHESIS ; GLYCOSIDIC LINKAGES ; MEDIATED FORMATION ; O-GLYCOSIDES ; GLYCOSYLATION ; DONORS ; ANHYDRIDE ; STRATEGY ; MILD
英文摘要:

Bromodimethylsulfonium bromide (BDMS) in combination with silver triflate provides a very efficient thiophilic promoter system, capable of activating both "disarmed" and "armed" thioglycosides for glycosidic bond formation. The usefulness of this new promoter is illustrated by a successful reactivity-based one-pot oligosaccharide assembly.

语种: 英语
所属项目编号: 973 ; 863
项目资助者: National Natural Science Foundation of China ; Ministry of Science and Technology of China
WOS记录号: WOS:000258503600006
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/50531
Appears in Collections:北京大学药学院_期刊论文

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作者单位: Peking Univ, State Key Lab Nat & Biomimet Drugs, Sch Pharmaceut Sci, Beijing 100083, Peoples R China

Recommended Citation:
Xiong, De-Cai,Zhang, Li-He,Ye, Xin-Shan. Bromodimethylsulfonium bromide-silver triflate: A new powerful promoter system for the activation of thioglycosides[J]. ADVANCED SYNTHESIS & CATALYSIS,2008,350(11-12):1696-1700.
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