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学科主题: 药学
题名:
Fe-catalyzed highly selective ring expansion of alkynylcyclopropyl alkanols to cyclobutanols
作者: Chen, Anjun1,2; Lin, Riyuan1; Liu, Qingjian2; Jiao, Ning1,3
刊名: CHEMICAL COMMUNICATIONS
发表日期: 2009
DOI: 10.1039/b916623h
期: 44, 页:6842-6844
收录类别: SCI ; IC ; CCR
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
关键词[WOS]: C BOND ACTIVATION ; ORGANIC-SYNTHESIS ; CYCLOADDITION REACTIONS ; COUPLING REACTION ; BUILDING-BLOCKS ; LEWIS-ACID ; METAL ; IRON ; METHYLENECYCLOPROPANES ; REARRANGEMENT
英文摘要:

A Fe-catalytic highly selective ring expansion reaction of alkynylcyclopropyl alkanols to alkynylcyclobutanols via a 1,2-carbon shift under mild conditions was developed. A new class of homogeneous FeCl(2)/O(2) catalytic system was employed in these novel transformations.

语种: 英语
所属项目编号: 20702002 ; 20872003 ; 20070001808 ; 2009CB825300
项目资助者: National Science Foundation of China ; PhD Programs Foundation of Ministry of Education of China ; National Basic Research Program of China
WOS记录号: WOS:000271506700045
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/51246
Appears in Collections:北京大学药学院_期刊论文

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作者单位: 1.Peking Univ, State Key Lab Nat & Biomimet Drugs, Sch Pharmaceut Sci, Beijing 100191, Peoples R China
2.Shandong Normal Univ, Dept Chem, Jinan 250014, Peoples R China
3.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

Recommended Citation:
Chen, Anjun,Lin, Riyuan,Liu, Qingjian,et al. Fe-catalyzed highly selective ring expansion of alkynylcyclopropyl alkanols to cyclobutanols[J]. CHEMICAL COMMUNICATIONS,2009(44):6842-6844.
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