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Highly enantioselective Michael addition of cyclopentanone with chalcones via novel di-iminium mechanism
Wang, Junfeng; Wang, Xin; Ge, Zemei; Cheng, Tieming; Li, Runtao
刊名CHEMICAL COMMUNICATIONS
2010
DOI10.1039/b915852a
46期:10页:1751-1753
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Multidisciplinary
资助者National Natural Science Foundation of China ; National Key Technology RD Program ; National Natural Science Foundation of China ; National Key Technology RD Program
研究领域[WOS]Chemistry
关键词[WOS]ASYMMETRIC CONJUGATE ADDITION ; ALDEHYDES ; KETONES ; CATALYST ; ENONES ; ORGANOCATALYST ; NITROALKANES ; NITROOLEFINS
英文摘要

The highly efficient asymmetric Michael addition reactions of cyclopentanone with chalcones were catalyzed by a simple and commercially available chiral 1,2-diaminocyclohexane-hexanedioic acid, and exhibited good yields (up to 92%) and excellent enantioselectivities (up to 99% ee). A new di-iminium mechanism for the reaction was proposed.

语种英语
所属项目编号20572004 ; 2007BAI34B00
资助者National Natural Science Foundation of China ; National Key Technology RD Program ; National Natural Science Foundation of China ; National Key Technology RD Program
WOS记录号WOS:000274827000048
引用统计
被引频次:32[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/51515
专题北京大学药学院
作者单位Peking Univ, State Key Lab Nat & Biomimet Drugs, Sch Pharmaceut Sci, Beijing 100191, Peoples R China
推荐引用方式
GB/T 7714
Wang, Junfeng,Wang, Xin,Ge, Zemei,et al. Highly enantioselective Michael addition of cyclopentanone with chalcones via novel di-iminium mechanism[J]. CHEMICAL COMMUNICATIONS,2010,46(10):1751-1753.
APA Wang, Junfeng,Wang, Xin,Ge, Zemei,Cheng, Tieming,&Li, Runtao.(2010).Highly enantioselective Michael addition of cyclopentanone with chalcones via novel di-iminium mechanism.CHEMICAL COMMUNICATIONS,46(10),1751-1753.
MLA Wang, Junfeng,et al."Highly enantioselective Michael addition of cyclopentanone with chalcones via novel di-iminium mechanism".CHEMICAL COMMUNICATIONS 46.10(2010):1751-1753.
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