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学科主题: 药学
题名:
Copper-Catalyzed Oxidative Transformation of Aryl Propargylic Azides to Aryl Propiolonitriles
作者: Wang, Teng1,2; Yin, Hang1; Jiao, Ning1,3
关键词: azides ; copper ; dehydrogenation ; nitriles ; oxidation ; Schmidt rearrangement
刊名: ADVANCED SYNTHESIS & CATALYSIS
发表日期: 2013-04-01
DOI: 10.1002/adsc.201201056
卷: 355, 期:6, 页:1207-1210
收录类别: SCI ; CCR
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Applied ; Chemistry, Organic
研究领域[WOS]: Chemistry
关键词[WOS]: C-H BONDS ; DEHYDROGENATIVE COUPLING REACTIONS ; PRIMARY AMIDES ; ALDEHYDE N,N-DIMETHYLHYDRAZONES ; HETEROGENEOUS CATALYST ; ALKENYL NITRILES ; TRANSITION-METAL ; DIRECT CYANATION ; TERTIARY-AMINES ; AQUEOUS AMMONIA
英文摘要:

A concise copper(I)-catalyzed oxidative transformation of aryl propargyl azides to aryl propiolonitriles has been developed. Aryl propiolonitrile derivatives can be obtained in moderate to good yields by this strategy. An oxidative Schmidt rearrangement is involved in this transformation.

语种: 英语
所属项目编号: 2009CB825300 ; 21172006
项目资助者: National Basic Research Program of China (973 Program) ; National Science Foundation of China ; Peking University
WOS记录号: WOS:000318042100020
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/52526
Appears in Collections:北京大学药学院_期刊论文

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作者单位: 1.Tianjin Univ, Dept Chem, Tianjin 300072, Peoples R China
2.Peking Univ, State Key Lab Nat & Biomimet Drugs, Sch Pharmaceut Sci, Beijing 100191, Peoples R China
3.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

Recommended Citation:
Wang, Teng,Yin, Hang,Jiao, Ning. Copper-Catalyzed Oxidative Transformation of Aryl Propargylic Azides to Aryl Propiolonitriles[J]. ADVANCED SYNTHESIS & CATALYSIS,2013,355(6):1207-1210.
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