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Copper-Catalyzed Oxidative Transformation of Aryl Propargylic Azides to Aryl Propiolonitriles
Wang, Teng1,2; Yin, Hang1; Jiao, Ning1,3
关键词Azides Copper Dehydrogenation Nitriles Oxidation Schmidt Rearrangement
刊名ADVANCED SYNTHESIS & CATALYSIS
2013-04-01
DOI10.1002/adsc.201201056
355期:6页:1207-1210
收录类别SCI ; CCR
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Applied ; Chemistry, Organic
资助者National Basic Research Program of China (973 Program) ; National Science Foundation of China ; Peking University ; National Basic Research Program of China (973 Program) ; National Science Foundation of China ; Peking University
研究领域[WOS]Chemistry
关键词[WOS]C-H BONDS ; DEHYDROGENATIVE COUPLING REACTIONS ; PRIMARY AMIDES ; ALDEHYDE N,N-DIMETHYLHYDRAZONES ; HETEROGENEOUS CATALYST ; ALKENYL NITRILES ; TRANSITION-METAL ; DIRECT CYANATION ; TERTIARY-AMINES ; AQUEOUS AMMONIA
英文摘要

A concise copper(I)-catalyzed oxidative transformation of aryl propargyl azides to aryl propiolonitriles has been developed. Aryl propiolonitrile derivatives can be obtained in moderate to good yields by this strategy. An oxidative Schmidt rearrangement is involved in this transformation.

语种英语
所属项目编号2009CB825300 ; 21172006
资助者National Basic Research Program of China (973 Program) ; National Science Foundation of China ; Peking University ; National Basic Research Program of China (973 Program) ; National Science Foundation of China ; Peking University
WOS记录号WOS:000318042100020
引用统计
被引频次:10[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/52526
专题北京大学药学院
作者单位1.Tianjin Univ, Dept Chem, Tianjin 300072, Peoples R China
2.Peking Univ, State Key Lab Nat & Biomimet Drugs, Sch Pharmaceut Sci, Beijing 100191, Peoples R China
3.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
推荐引用方式
GB/T 7714
Wang, Teng,Yin, Hang,Jiao, Ning. Copper-Catalyzed Oxidative Transformation of Aryl Propargylic Azides to Aryl Propiolonitriles[J]. ADVANCED SYNTHESIS & CATALYSIS,2013,355(6):1207-1210.
APA Wang, Teng,Yin, Hang,&Jiao, Ning.(2013).Copper-Catalyzed Oxidative Transformation of Aryl Propargylic Azides to Aryl Propiolonitriles.ADVANCED SYNTHESIS & CATALYSIS,355(6),1207-1210.
MLA Wang, Teng,et al."Copper-Catalyzed Oxidative Transformation of Aryl Propargylic Azides to Aryl Propiolonitriles".ADVANCED SYNTHESIS & CATALYSIS 355.6(2013):1207-1210.
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