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Synthesis of the cycloheptannelated indole fragment of dragmacidin E
Wang, Bin1; Qin, Hua1; Zhang, Fengying1; Jia, Yanxing1,2
关键词Indole Alkaloid Dragmacidin e Total Synthesis Natural Product
刊名TETRAHEDRON LETTERS
2014-02-26
DOI10.1016/j.tetlet.2014.01.063
55期:9页:1561-1563
收录类别SCI ; IC
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]WATER MARINE SPONGE ; EFFICIENT TOTAL-SYNTHESIS ; CROSS-COUPLING REACTIONS ; SUZUKI-MIYAURA REACTION ; 1ST TOTAL-SYNTHESIS ; ENANTIOSELECTIVE SYNTHESIS ; DIHYDROHAMACANTHIN-A ; BIOMIMETIC SYNTHESIS ; (+)-LYSERGIC ACID ; CLAVICIPITIC ACID
英文摘要

Synthesis of the pivotal cycloheptannelated indole fragment of indole alkaloid dragmacidin E is achieved. The synthesis features a Pd-catalyzed indole synthesis reaction for the preparation of 3,7-disubstituted indole, a regioselective intramolecular Friedel Crafts reaction for the construction of the 3,4-bridged cycloheptannelated indole skeleton, and a coupling reaction of vinyl triflate with diorganocuprate. (C) 2014 Elsevier Ltd. All rights reserved.

语种英语
WOS记录号WOS:000332434000012
项目编号21290180 ; 20972007 ; 2010CB833200 ; 20120001110100
资助机构State Key Laboratory of Drug Research ; National Natural Science Foundation of China ; National Basic Research Program of China (973 Program) ; Foundation of Ministry of Education of China
引用统计
被引频次:8[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/52929
专题北京大学药学院
作者单位1.Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Mat Media, State Key Lab Drug Res, Shanghai 201203, Peoples R China
推荐引用方式
GB/T 7714
Wang, Bin,Qin, Hua,Zhang, Fengying,et al. Synthesis of the cycloheptannelated indole fragment of dragmacidin E[J]. TETRAHEDRON LETTERS,2014,55(9):1561-1563.
APA Wang, Bin,Qin, Hua,Zhang, Fengying,&Jia, Yanxing.(2014).Synthesis of the cycloheptannelated indole fragment of dragmacidin E.TETRAHEDRON LETTERS,55(9),1561-1563.
MLA Wang, Bin,et al."Synthesis of the cycloheptannelated indole fragment of dragmacidin E".TETRAHEDRON LETTERS 55.9(2014):1561-1563.
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