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学科主题: 药学
题名:
Synthesis of the cycloheptannelated indole fragment of dragmacidin E
作者: Wang, Bin1; Qin, Hua1; Zhang, Fengying1; Jia, Yanxing1,2
关键词: Indole alkaloid ; Dragmacidin E ; Total synthesis ; Natural product
刊名: TETRAHEDRON LETTERS
发表日期: 2014-02-26
DOI: 10.1016/j.tetlet.2014.01.063
卷: 55, 期:9, 页:1561-1563
收录类别: SCI ; IC
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
关键词[WOS]: WATER MARINE SPONGE ; EFFICIENT TOTAL-SYNTHESIS ; CROSS-COUPLING REACTIONS ; SUZUKI-MIYAURA REACTION ; 1ST TOTAL-SYNTHESIS ; ENANTIOSELECTIVE SYNTHESIS ; DIHYDROHAMACANTHIN-A ; BIOMIMETIC SYNTHESIS ; (+)-LYSERGIC ACID ; CLAVICIPITIC ACID
英文摘要:

Synthesis of the pivotal cycloheptannelated indole fragment of indole alkaloid dragmacidin E is achieved. The synthesis features a Pd-catalyzed indole synthesis reaction for the preparation of 3,7-disubstituted indole, a regioselective intramolecular Friedel Crafts reaction for the construction of the 3,4-bridged cycloheptannelated indole skeleton, and a coupling reaction of vinyl triflate with diorganocuprate. (C) 2014 Elsevier Ltd. All rights reserved.

语种: 英语
所属项目编号: 21290180 ; 20972007 ; 2010CB833200 ; 20120001110100
项目资助者: State Key Laboratory of Drug Research ; National Natural Science Foundation of China ; National Basic Research Program of China (973 Program) ; Foundation of Ministry of Education of China
WOS记录号: WOS:000332434000012
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/52929
Appears in Collections:北京大学药学院_期刊论文

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作者单位: 1.Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Mat Media, State Key Lab Drug Res, Shanghai 201203, Peoples R China

Recommended Citation:
Wang, Bin,Qin, Hua,Zhang, Fengying,et al. Synthesis of the cycloheptannelated indole fragment of dragmacidin E[J]. TETRAHEDRON LETTERS,2014,55(9):1561-1563.
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