北京大学医学部机构知识库
Advanced  
IR@PKUHSC  > 北京大学药学院  > 期刊论文
学科主题: 药学
题名:
SmI2-Mediated Carbon-Carbon Bond Fragmentation in alpha-Aminomethyl Malonates
作者: Xu, Qiongfeng1,2,3; Cheng, Bin2,3,4,5; Ye, Xinshan1; Zhai, Hongbin1,2,3
刊名: ORGANIC LETTERS
发表日期: 2009-09-17
DOI: 10.1021/ol901608k
卷: 11, 期:18, 页:4136-4138
收录类别: SCI ; IC ; CCR
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
关键词[WOS]: FREE-RADICAL FRAGMENTATION ; RING-OPENING REACTIONS ; SAMARIUM(II) IODIDE ; ORGANIC-SYNTHESIS ; FACILE SYNTHESIS ; DIIODIDE ; REDUCTIONS ; SMI2 ; KETONES ; DERIVATIVES
英文摘要:

A new and efficient samarium diiodide-promoted carbon-carbon bond fragmentation reaction of alpha-aminomethyl malonates, taking place normally at room temperature and generating the corresponding deaminomethylation products in 74-94% yields, is reported. The presence of the amino group is necessary for the success of the current transformation.

语种: 英语
所属项目编号: 20625204 ; 20632030 ; 90713007 ; 20772141 ; 2006AA09Z405 ; 2006AA09Z446
项目资助者: NSFC ; MOST_863
WOS记录号: WOS:000269670700028
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/53462
Appears in Collections:北京大学药学院_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100083, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Synthet Chem Nat Subst, Shanghai 200032, Peoples R China
3.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Bioorgan & Nat Prod Chem, Shanghai 200032, Peoples R China
4.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China
5.Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China

Recommended Citation:
Xu, Qiongfeng,Cheng, Bin,Ye, Xinshan,et al. SmI2-Mediated Carbon-Carbon Bond Fragmentation in alpha-Aminomethyl Malonates[J]. ORGANIC LETTERS,2009,11(18):4136-4138.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[Xu, Qiongfeng]'s Articles
[Cheng, Bin]'s Articles
[Ye, Xinshan]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[Xu, Qiongfeng]‘s Articles
[Cheng, Bin]‘s Articles
[Ye, Xinshan]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Copyright © 2007-2017  北京大学医学部 - Feedback
Powered by CSpace