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学科主题: 药学
题名:
SmI2-Mediated Carbon-Carbon Bond Fragmentation in alpha-Aminomethyl Malonates
作者: Xu, Qiongfeng1,2,3; Cheng, Bin2,3,4,5; Ye, Xinshan1; Zhai, Hongbin1,2,3
刊名: ORGANIC LETTERS
发表日期: 2009-09-17
DOI: 10.1021/ol901608k
卷: 11, 期:18, 页:4136-4138
收录类别: SCI ; IC ; CCR
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
关键词[WOS]: FREE-RADICAL FRAGMENTATION ; RING-OPENING REACTIONS ; SAMARIUM(II) IODIDE ; ORGANIC-SYNTHESIS ; FACILE SYNTHESIS ; DIIODIDE ; REDUCTIONS ; SMI2 ; KETONES ; DERIVATIVES
英文摘要:

A new and efficient samarium diiodide-promoted carbon-carbon bond fragmentation reaction of alpha-aminomethyl malonates, taking place normally at room temperature and generating the corresponding deaminomethylation products in 74-94% yields, is reported. The presence of the amino group is necessary for the success of the current transformation.

语种: 英语
所属项目编号: 20625204 ; 20632030 ; 90713007 ; 20772141 ; 2006AA09Z405 ; 2006AA09Z446
项目资助者: NSFC ; MOST_863
WOS记录号: WOS:000269670700028
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/53462
Appears in Collections:北京大学药学院_期刊论文

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作者单位: 1.Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100083, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Synthet Chem Nat Subst, Shanghai 200032, Peoples R China
3.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Bioorgan & Nat Prod Chem, Shanghai 200032, Peoples R China
4.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China
5.Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China

Recommended Citation:
Xu, Qiongfeng,Cheng, Bin,Ye, Xinshan,et al. SmI2-Mediated Carbon-Carbon Bond Fragmentation in alpha-Aminomethyl Malonates[J]. ORGANIC LETTERS,2009,11(18):4136-4138.
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