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Et3N-catalyzed oxidative dehydrogenative coupling of alpha-unsubstituted aldehydes and ketones with aryl diamines leading to quinoxalines using molecular oxygen as oxidant
Zhang, Chun1; Xu, Zejun1; Zhang, Liangren1; Jiao, Ning1,2
关键词C-h Activation Aerobic Oxidation Dehydrogenation Organocatalysis Metal Free Molecular Oxygen
刊名TETRAHEDRON
2012-07-01
DOI10.1016/j.tet.2012.03.020
68期:26页:5258-5262
收录类别SCI ; CCR
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Organic
资助者National Basic Research Program of China (973 Program) ; National Science Foundation of China ; Peking-University ; National Basic Research Program of China (973 Program) ; National Science Foundation of China ; Peking-University
研究领域[WOS]Chemistry
关键词[WOS]H BOND ACTIVATION ; ONE-POT SYNTHESIS ; C-H ; CATALYZED OXIDATION ; DIOXYGEN ACTIVATION ; BIOLOGICAL-ACTIVITY ; AEROBIC OXIDATION ; ELECTRON-TRANSFER ; FACILE SYNTHESIS ; TERT-BUTOXIDE
英文摘要

A novel Et3N-catalyzed oxidative dehydrogenative coupling of alpha-unsubstituted carbonyl compounds with aryl diamines leading to quinoxaline derivatives using molecular oxygen as oxidant has been developed. Six hydrogen dissociations involving 2 sp(3) C-H bonds activation are realized under mild conditions in this approach. Plausible mechanism is proposed for this novel Et3N-catalyzed transformation on the basis of the aboratively designed mechanistic studies including the radical detection by EPR. (C) 2012 Elsevier Science. All rights reserved. (C) 2012 Elsevier Ltd. All rights reserved.

语种英语
所属项目编号2009CB825300 ; 20872003 ; 21172006
资助者National Basic Research Program of China (973 Program) ; National Science Foundation of China ; Peking-University ; National Basic Research Program of China (973 Program) ; National Science Foundation of China ; Peking-University
WOS记录号WOS:000305381700022
引用统计
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/53494
专题北京大学药学院
作者单位1.Peking Univ, State Key Lab Nat & Biomimet Drugs, Sch Pharmaceut Sci, Beijing 100191, Peoples R China
2.E China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Chun,Xu, Zejun,Zhang, Liangren,et al. Et3N-catalyzed oxidative dehydrogenative coupling of alpha-unsubstituted aldehydes and ketones with aryl diamines leading to quinoxalines using molecular oxygen as oxidant[J]. TETRAHEDRON,2012,68(26):5258-5262.
APA Zhang, Chun,Xu, Zejun,Zhang, Liangren,&Jiao, Ning.(2012).Et3N-catalyzed oxidative dehydrogenative coupling of alpha-unsubstituted aldehydes and ketones with aryl diamines leading to quinoxalines using molecular oxygen as oxidant.TETRAHEDRON,68(26),5258-5262.
MLA Zhang, Chun,et al."Et3N-catalyzed oxidative dehydrogenative coupling of alpha-unsubstituted aldehydes and ketones with aryl diamines leading to quinoxalines using molecular oxygen as oxidant".TETRAHEDRON 68.26(2012):5258-5262.
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