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学科主题药学
Multiple Oxidative Dehydrogenative Functionalization of Arylacetaldehydes Using Molecular Oxygen as Oxidant Leading to 2-Oxo-acetamidines
Zhang, Chun1; Zhang, Liangren1; Jiao, Ning1,2
关键词Copper Cross-coupling Dehydrogenation Oxidation Oxygen
刊名ADVANCED SYNTHESIS & CATALYSIS
2012-05-01
DOI10.1002/adsc.201100892
354期:7页:1293-1300
收录类别SCI ; IC ; CCR
文章类型Review
WOS标题词Science & Technology
类目[WOS]Chemistry, Applied ; Chemistry, Organic
资助者Peking University ; National Science Foundation of China ; National Basic Research Program of China (973 Program) ; Peking University ; National Science Foundation of China ; National Basic Research Program of China (973 Program)
研究领域[WOS]Chemistry
关键词[WOS]C-H BOND ; COPPER-CATALYZED TRIFLUOROMETHYLATION ; CARBON-HYDROGEN BONDS ; TERMINAL ALKYNES ; N-HYDROXYPHTHALIMIDE ; DIOXYGEN ACTIVATION ; COUPLING REACTIONS ; ORTHO-BORYLATION ; PALLADIUM ; EFFICIENT
英文摘要

A novel copper-catalyzed, multiple oxidative dehydrogenative functionalization of arylacetaldehydes leading to 2-oxo-acetamidine compounds has been developed. This transformation is highly efficient with dissociation of six hydrogens including two sp3 C?H and one sp2 C?H bond activations. This method not only provides an efficient approach to 2-oxo-acetamidine compounds, but also offers a valuable mechanistic insight into this novel copper catalysis.

语种英语
所属项目编号20872003 ; 2009CB825300
资助者Peking University ; National Science Foundation of China ; National Basic Research Program of China (973 Program) ; Peking University ; National Science Foundation of China ; National Basic Research Program of China (973 Program)
WOS记录号WOS:000303495900010
Citation statistics
Cited Times:23[WOS]   [WOS Record]     [Related Records in WOS]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/53502
Collection北京大学药学院
作者单位1.Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
2.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Chun,Zhang, Liangren,Jiao, Ning. Multiple Oxidative Dehydrogenative Functionalization of Arylacetaldehydes Using Molecular Oxygen as Oxidant Leading to 2-Oxo-acetamidines[J]. ADVANCED SYNTHESIS & CATALYSIS,2012,354(7):1293-1300.
APA Zhang, Chun,Zhang, Liangren,&Jiao, Ning.(2012).Multiple Oxidative Dehydrogenative Functionalization of Arylacetaldehydes Using Molecular Oxygen as Oxidant Leading to 2-Oxo-acetamidines.ADVANCED SYNTHESIS & CATALYSIS,354(7),1293-1300.
MLA Zhang, Chun,et al."Multiple Oxidative Dehydrogenative Functionalization of Arylacetaldehydes Using Molecular Oxygen as Oxidant Leading to 2-Oxo-acetamidines".ADVANCED SYNTHESIS & CATALYSIS 354.7(2012):1293-1300.
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