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Benzenesulfinyl morpholine: A new promoter for one-pot oligosaccharide synthesis using thioglycosides by pre-activation strategy
Wang, Changning; Wang, Haisheng; Huang, Xuefei; Zhang, Li-He; Ye, Xin-Shan
关键词Benzenesulfinyl Morpholine Promoter Thioglycoside Pre-activation One-pot Oligosaccharide Assembly
刊名SYNLETT
2006-10-17
DOI10.1055/s-2006-950247
17页:2846-2850
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]ORTHOGONAL GLYCOSYLATION STRATEGY ; SOLID-PHASE SYNTHESIS ; CHEMOSELECTIVE GLYCOSYLATIONS ; TRIFLUOROMETHANESULFONIC ANHYDRIDE ; ITERATIVE GLYCOSYLATION ; COMBINATORIAL SYNTHESIS ; GLYCOSIDIC LINKAGES ; CHEMICAL-SYNTHESIS ; BUILDING-BLOCKS ; REACTIVITY
英文摘要

Benzenesulfinyl morpholine (BSM) has been applied as a new promoter for the activation of thioglycosides. This proceeds by the in situ reaction of BSM with trifluoromethanesulfonic anhydride, which subsequently activates thioglycosides for glycosyla- tions. Importantly, this reagent works well in our pre-activation one-pot oligosaccharide assembly strategy.

语种英语
WOS记录号WOS:000242059100036
引用统计
被引频次:38[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/53646
专题北京大学药学院
作者单位1.Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Bioimet Drugs, Beijing 100083, Peoples R China
2.Univ Toledo, Dept Chem, Toledo, OH 43606 USA
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GB/T 7714
Wang, Changning,Wang, Haisheng,Huang, Xuefei,et al. Benzenesulfinyl morpholine: A new promoter for one-pot oligosaccharide synthesis using thioglycosides by pre-activation strategy[J]. SYNLETT,2006(17):2846-2850.
APA Wang, Changning,Wang, Haisheng,Huang, Xuefei,Zhang, Li-He,&Ye, Xin-Shan.(2006).Benzenesulfinyl morpholine: A new promoter for one-pot oligosaccharide synthesis using thioglycosides by pre-activation strategy.SYNLETT(17),2846-2850.
MLA Wang, Changning,et al."Benzenesulfinyl morpholine: A new promoter for one-pot oligosaccharide synthesis using thioglycosides by pre-activation strategy".SYNLETT .17(2006):2846-2850.
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