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NHC-catalyzed C-O or C-N bond formation: efficient approaches to alpha,beta-unsaturated esters and amides
Zhang, Bo1; Feng, Peng1; Cui, Yuxin1; Jiao, Ning1,2
刊名CHEMICAL COMMUNICATIONS
2012
DOI10.1039/c2cc32862c
48期:58页:7280-7282
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Multidisciplinary
资助者National Basic Research Program of China (973 Program) ; National Science Foundation of China ; Peking University ; National Basic Research Program of China (973 Program) ; National Science Foundation of China ; Peking University
研究领域[WOS]Chemistry
关键词[WOS]STEREOSELECTIVE-SYNTHESIS ; ESTERIFICATION CATALYSTS ; ACTIVATED CARBOXYLATES ; NUCLEOPHILIC CARBENES ; ALDEHYDES ; GENERATION ; CONVERSION ; COMPLEXES ; NITRILES ; REAGENTS
英文摘要

Simple and efficient NHC-catalyzed transformations of bromoenal or alpha,beta-dibromoenal into alpha,beta-unsaturated esters or amides with high stereoselectivity through C-O or C-N bond formation have been demonstrated. The NHC-catalyzed processes occur under mild conditions. The ready availability of the starting materials, avoidance of external oxidants and the usefulness of the products all make the strategy attractive.

语种英语
所属项目编号2009CB825300 ; 21172006
资助者National Basic Research Program of China (973 Program) ; National Science Foundation of China ; Peking University ; National Basic Research Program of China (973 Program) ; National Science Foundation of China ; Peking University
WOS记录号WOS:000305624500016
Citation statistics
Cited Times:34[WOS]   [WOS Record]     [Related Records in WOS]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/53792
Collection北京大学药学院
作者单位1.Peking Univ, State Key Lab Nat & Biomimet Drugs, Sch Pharmaceut Sci, Beijing 100191, Peoples R China
2.E China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Bo,Feng, Peng,Cui, Yuxin,et al. NHC-catalyzed C-O or C-N bond formation: efficient approaches to alpha,beta-unsaturated esters and amides[J]. CHEMICAL COMMUNICATIONS,2012,48(58):7280-7282.
APA Zhang, Bo,Feng, Peng,Cui, Yuxin,&Jiao, Ning.(2012).NHC-catalyzed C-O or C-N bond formation: efficient approaches to alpha,beta-unsaturated esters and amides.CHEMICAL COMMUNICATIONS,48(58),7280-7282.
MLA Zhang, Bo,et al."NHC-catalyzed C-O or C-N bond formation: efficient approaches to alpha,beta-unsaturated esters and amides".CHEMICAL COMMUNICATIONS 48.58(2012):7280-7282.
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