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学科主题: 药学
题名:
Efficient synthesis of 8-oxa-bicyclo[3.2.1] octane derivatives from D-arabinose
作者: Liu, Yi; Han, Tian-Xiang; Yang, Zhen-Jun; Zhang, Liang-Ren; Zhang, Li-He
刊名: TETRAHEDRON-ASYMMETRY
发表日期: 2007-09-27
DOI: 10.1016/j.tetasy.2007.08.033
卷: 18, 期:19, 页:2326-2331
收录类别: SCI ; IC ; CCR
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Inorganic & Nuclear ; Chemistry, Organic ; Chemistry, Physical
研究领域[WOS]: Chemistry
关键词[WOS]: RING-CLOSING METATHESIS ; GENERAL-ROUTE ; ANALOGS ; CYCLOADDITION ; CYCLIZATION ; 1ST ; B-2 ; REARRANGEMENT ; CARBOCYCLES ; CARBASUGAR
英文摘要:

Our studies of the TIBAL-promoted Claisen rearrangement reaction and ring-closing metathesis (RCM) resulted in the development of an e. fficient synthetic route to polyfunctional seven-membered carbasugar synthons from D- arabinose. Moreover, the construction of 8-oxa-bicyclo[3.2.1] octane derivatives 10 and 13 was achieved by BCl3 or iodide- promoted intramolecular electrophilic addition reactions, which were regio- and stereoselective. (c) 2007 Elsevier Ltd. All rights reserved.

语种: 英语
WOS记录号: WOS:000252095300006
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/54193
Appears in Collections:北京大学药学院_期刊论文

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作者单位: Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100083, Peoples R China

Recommended Citation:
Liu, Yi,Han, Tian-Xiang,Yang, Zhen-Jun,et al. Efficient synthesis of 8-oxa-bicyclo[3.2.1] octane derivatives from D-arabinose[J]. TETRAHEDRON-ASYMMETRY,2007,18(19):2326-2331.
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