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Synthesis of catechins via thiourea/AuCl(3)-catalyzed cycloalkylation of aryl epoxides
Liu, Yongxiang; Li, Xiben; Lin, Guang; Xiang, Zheng; Xiang, Jing; Zhao, Mingzhe; Chen, Jiahua1; Yang, Zhen
刊名JOURNAL OF ORGANIC CHEMISTRY
2008-06-20
DOI10.1021/jo8005649
73期:12页:4625-4629
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]H BOND ACTIVATION ; ELECTRON-RICH ARENES ; GREEN TEA CATECHINS ; CANCER-CELL GROWTH ; POLYPHENOL CHEMISTRY ; ENANTIOSELECTIVE SYNTHESIS ; EPIGALLOCATECHIN GALLATE ; ASYMMETRIC EPOXIDATION ; STAPHYLOCOCCUS-AUREUS ; KINETIC RESOLUTION
英文摘要

A diversity-oriented approach for the synthesis of structurally diverse catechins was achieved in good yields via thiourea/AuCl(3)/AgOTf-catalyzed annulations of aryl epoxides under mild conditions. This new protocol provides a highly efficient entry to a library of catechins-derived natural products, notably anti-HIV, agent 8-C-ascorbyl-(-)-epigallocatechin.

语种英语
WOS记录号WOS:000256757100033
引用统计
被引频次:27[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/54619
专题北京大学药学院
作者单位1.Peking Univ, BNMLS, Coll Chem, Beijing 100871, Peoples R China
2.Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, Beijing 100871, Peoples R China
3.Peking Univ, Lab Chem Genom, Shenzhen Grad Sch, Beijing 100871, Peoples R China
4.Peking Univ, State Key Lab Nat & Biomimet Drugs, Sch Pharmaceut Sci, Beijing 100871, Peoples R China
推荐引用方式
GB/T 7714
Liu, Yongxiang,Li, Xiben,Lin, Guang,et al. Synthesis of catechins via thiourea/AuCl(3)-catalyzed cycloalkylation of aryl epoxides[J]. JOURNAL OF ORGANIC CHEMISTRY,2008,73(12):4625-4629.
APA Liu, Yongxiang.,Li, Xiben.,Lin, Guang.,Xiang, Zheng.,Xiang, Jing.,...&Yang, Zhen.(2008).Synthesis of catechins via thiourea/AuCl(3)-catalyzed cycloalkylation of aryl epoxides.JOURNAL OF ORGANIC CHEMISTRY,73(12),4625-4629.
MLA Liu, Yongxiang,et al."Synthesis of catechins via thiourea/AuCl(3)-catalyzed cycloalkylation of aryl epoxides".JOURNAL OF ORGANIC CHEMISTRY 73.12(2008):4625-4629.
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