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Dioxygen Activation under Ambient Conditions: Cu-Catalyzed Oxidative Amidation-Diketonization of Terminal Alkynes Leading to alpha-Ketoamides
Zhang, Chun1; Jiao, Ning1,2
刊名JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
2010-01-13
DOI10.1021/ja908911n
132期:1页:28-+
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Multidisciplinary
资助者Peking University ; National Natural Science Foundation of China ; National Basic Research Program of China ; Peking University ; National Natural Science Foundation of China ; National Basic Research Program of China
研究领域[WOS]Chemistry
关键词[WOS]MOLECULAR-OXYGEN ; H ACTIVATION ; RADICALS ; SUPEROXIDE ; TEMPO ; CYCLIZATION ; ALCOHOLS ; OXIDANT ; AMINYL ; BOND
英文摘要

A novel Cu-catalyzed oxidative amidation-diketonization reaction of terminal alkynes leading to alpha-ketoamides has been developed. This chemistry offers a valuable mechanistic insight into this novel Cu catalysis via a radical process. O(2) not only participates as the ideal oxidant but also undergoes dioxygen activation under ambient conditions in this transformation.

语种英语
所属项目编号20702002 ; 20872003 ; 2009CB825300
资助者Peking University ; National Natural Science Foundation of China ; National Basic Research Program of China ; Peking University ; National Natural Science Foundation of China ; National Basic Research Program of China
WOS记录号WOS:000275084400014
引用统计
被引频次:266[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/55038
专题北京大学药学院
作者单位1.Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
2.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Chun,Jiao, Ning. Dioxygen Activation under Ambient Conditions: Cu-Catalyzed Oxidative Amidation-Diketonization of Terminal Alkynes Leading to alpha-Ketoamides[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2010,132(1):28-+.
APA Zhang, Chun,&Jiao, Ning.(2010).Dioxygen Activation under Ambient Conditions: Cu-Catalyzed Oxidative Amidation-Diketonization of Terminal Alkynes Leading to alpha-Ketoamides.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,132(1),28-+.
MLA Zhang, Chun,et al."Dioxygen Activation under Ambient Conditions: Cu-Catalyzed Oxidative Amidation-Diketonization of Terminal Alkynes Leading to alpha-Ketoamides".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 132.1(2010):28-+.
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