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学科主题: 药学
题名:
An efficient organocatalytic enantioselective Michael addition of aryl methyl ketones with 2-furanones: highly functionalized chiral 3,4-substituted lactones
作者: Wang, Wei; Wang, Junfeng; Zhou, Shuo; Sun, Qi; Ge, Zemei; Wang, Xin; Li, Runtao
刊名: CHEMICAL COMMUNICATIONS
发表日期: 2013
DOI: 10.1039/c2cc35488h
卷: 49, 期:13, 页:1333-1335
收录类别: SCI ; IC ; CCR
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
关键词[WOS]: ALDOL REACTION ; CATALYSIS ; DERIVATIVES ; ACID
英文摘要:

The efficient asymmetric Michael addition reactions of aryl methyl ketones with 2-furanones were catalyzed by a simple and commercially available chiral 1,2-diphenyl-1,2-ethanediamine and p-TSA center dot H2O as cocatalyst with good yields (up to 95%) and excellent enantioselectivities (up to >99% ee). A bi-functional catalytic mechanism for the reaction was proposed.

语种: 英语
所属项目编号: 20972005
项目资助者: National Natural Science Foundation of China
WOS记录号: WOS:000313663900026
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/55347
Appears in Collections:北京大学药学院_期刊论文

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作者单位: Peking Univ, State Key Lab Nat & Biomimet Drugs, Sch Pharmaceut Sci, Beijing 100191, Peoples R China

Recommended Citation:
Wang, Wei,Wang, Junfeng,Zhou, Shuo,et al. An efficient organocatalytic enantioselective Michael addition of aryl methyl ketones with 2-furanones: highly functionalized chiral 3,4-substituted lactones[J]. CHEMICAL COMMUNICATIONS,2013,49(13):1333-1335.
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