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学科主题: 药学
题名:
The versatile roles of ammonium salt catalysts in enantioselective reduction and alkylation of alpha,beta-unsaturated aldehydes: iminium catalysis, enamine catalysis and acid catalysis
作者: Xiang, Shi-Kai1; Zhang, Bo1; Zhang, Li-He1; Cui, Yuxin1; Jiao, Ning1,2
刊名: CHEMICAL COMMUNICATIONS
发表日期: 2011
DOI: 10.1039/c1cc10124b
卷: 47, 期:17, 页:5007-5009
收录类别: SCI ; IC ; CCR
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
关键词[WOS]: ALPHA-ALLYLIC ALKYLATION ; ONE-POT ACCESS ; TRANSFER HYDROGENATION ; DOMINO REACTIONS ; ASYMMETRIC ALKYLATION ; CASCADE CATALYSIS ; MICHAEL ADDITION ; GAMMA-ALKYLATION ; HANTZSCH ESTERS ; IONIC LIQUIDS
英文摘要:

A novel strategy for highly efficient utilization of chiral ammonium salt catalysts has been described in this paper. Three kinds of catalytic functions including iminium catalysis, enamine catalysis, and acid catalysis of chiral ammonium salt catalysts, have been achieved in the enantioselective reduction and alkylation reaction of alpha,beta-unsaturated aldehydes with alcohols.

语种: 英语
所属项目编号: 20702002 ; 20872003 ; 2009CB825300
项目资助者: Peking University ; National Science Foundation of China ; National Basic Research Program of China (973 Program)
WOS记录号: WOS:000289523000045
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/55509
Appears in Collections:北京大学药学院_期刊论文

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作者单位: 1.Peking Univ, State Key Lab Nat & Biomimet Drugs, Sch Pharmaceut Sci, Beijing 100191, Peoples R China
2.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

Recommended Citation:
Xiang, Shi-Kai,Zhang, Bo,Zhang, Li-He,et al. The versatile roles of ammonium salt catalysts in enantioselective reduction and alkylation of alpha,beta-unsaturated aldehydes: iminium catalysis, enamine catalysis and acid catalysis[J]. CHEMICAL COMMUNICATIONS,2011,47(17):5007-5009.
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