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The versatile roles of ammonium salt catalysts in enantioselective reduction and alkylation of alpha,beta-unsaturated aldehydes: iminium catalysis, enamine catalysis and acid catalysis
Xiang, Shi-Kai1; Zhang, Bo1; Zhang, Li-He1; Cui, Yuxin1; Jiao, Ning1,2
刊名CHEMICAL COMMUNICATIONS
2011
DOI10.1039/c1cc10124b
47期:17页:5007-5009
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]ALPHA-ALLYLIC ALKYLATION ; ONE-POT ACCESS ; TRANSFER HYDROGENATION ; DOMINO REACTIONS ; ASYMMETRIC ALKYLATION ; CASCADE CATALYSIS ; MICHAEL ADDITION ; GAMMA-ALKYLATION ; HANTZSCH ESTERS ; IONIC LIQUIDS
英文摘要

A novel strategy for highly efficient utilization of chiral ammonium salt catalysts has been described in this paper. Three kinds of catalytic functions including iminium catalysis, enamine catalysis, and acid catalysis of chiral ammonium salt catalysts, have been achieved in the enantioselective reduction and alkylation reaction of alpha,beta-unsaturated aldehydes with alcohols.

语种英语
WOS记录号WOS:000289523000045
项目编号20702002 ; 20872003 ; 2009CB825300
资助机构Peking University ; National Science Foundation of China ; National Basic Research Program of China (973 Program)
引用统计
被引频次:22[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/55509
专题北京大学药学院
北京大学药学院_天然药物与仿生药物国家重点实验室
北京大学药学院_药物化学系
作者单位1.Peking Univ, State Key Lab Nat & Biomimet Drugs, Sch Pharmaceut Sci, Beijing 100191, Peoples R China
2.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
推荐引用方式
GB/T 7714
Xiang, Shi-Kai,Zhang, Bo,Zhang, Li-He,et al. The versatile roles of ammonium salt catalysts in enantioselective reduction and alkylation of alpha,beta-unsaturated aldehydes: iminium catalysis, enamine catalysis and acid catalysis[J]. CHEMICAL COMMUNICATIONS,2011,47(17):5007-5009.
APA Xiang, Shi-Kai,Zhang, Bo,Zhang, Li-He,Cui, Yuxin,&Jiao, Ning.(2011).The versatile roles of ammonium salt catalysts in enantioselective reduction and alkylation of alpha,beta-unsaturated aldehydes: iminium catalysis, enamine catalysis and acid catalysis.CHEMICAL COMMUNICATIONS,47(17),5007-5009.
MLA Xiang, Shi-Kai,et al."The versatile roles of ammonium salt catalysts in enantioselective reduction and alkylation of alpha,beta-unsaturated aldehydes: iminium catalysis, enamine catalysis and acid catalysis".CHEMICAL COMMUNICATIONS 47.17(2011):5007-5009.
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