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学科主题药学
KI-catalyzed imidation of sp(3) C-H bond adjacent to amide nitrogen atom
Lao, Zhi-Qi; Zhong, Wen-He; Lou, Qing-Hua; Li, Zhong-Jun; Meng, Xiang-Bao
刊名ORGANIC & BIOMOLECULAR CHEMISTRY
2012
DOI10.1039/c2ob26430g
10期:39页:7869-7871
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]DEHYDROGENATIVE COUPLING REACTIONS ; GLYCINE DERIVATIVES ; CARBOXYLIC-ACIDS ; TRANSITION-METAL ; FUNCTIONALIZATION ; AMIDATION ; ACTIVATION ; AMINATION ; SCOPE ; TETRAHYDROISOQUINOLINES
英文摘要

We have developed a new KI-catalyzed method for the imidation of an sp(3) C-H bond adjacent to an amide nitrogen atom by using TBHP (tert-butyl hydroperoxide, 70% aqueous solution) as the oxidant. This novel procedure tolerated air and moisture and provided a series of novel products in moderate to excellent yields under mild conditions.

语种英语
WOS记录号WOS:000308929500003
项目编号2012CB822100 ; 21072017 ; 21072016 ; 20972012
资助机构National Basic Research Program of China ; National Natural Science Foundation of China (NSFC)
引用统计
被引频次:50[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/55607
专题北京大学药学院_化学生物学系
作者单位Peking Univ, Dept Biol Chem, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs,Hlth Sci Ctr, Beijing 100191, Peoples R China
推荐引用方式
GB/T 7714
Lao, Zhi-Qi,Zhong, Wen-He,Lou, Qing-Hua,et al. KI-catalyzed imidation of sp(3) C-H bond adjacent to amide nitrogen atom[J]. ORGANIC & BIOMOLECULAR CHEMISTRY,2012,10(39):7869-7871.
APA Lao, Zhi-Qi,Zhong, Wen-He,Lou, Qing-Hua,Li, Zhong-Jun,&Meng, Xiang-Bao.(2012).KI-catalyzed imidation of sp(3) C-H bond adjacent to amide nitrogen atom.ORGANIC & BIOMOLECULAR CHEMISTRY,10(39),7869-7871.
MLA Lao, Zhi-Qi,et al."KI-catalyzed imidation of sp(3) C-H bond adjacent to amide nitrogen atom".ORGANIC & BIOMOLECULAR CHEMISTRY 10.39(2012):7869-7871.
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