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学科主题: 药学
题名:
Thia-Michael addition using cheap and odorless S-alkylisothiouronium salts as thiol equivalents in water
作者: Zhao, Yan; Ge, Ze-Mei; Cheng, Tie-Ming; Li, Run-Tao
关键词: thia-Michael addition ; thiol equivalent ; S-alkylisothiouronium salts ; electron-deficient olefins ; green chemistry
刊名: SYNLETT
发表日期: 2007-06-18
DOI: 10.1055/s-2007-982530
期: 10, 页:1529-1532
收录类别: SCI ; IC ; CCR
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
关键词[WOS]: SOLVENT-FREE CONDITIONS ; ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS ; CATALYZED CONJUGATE ADDITION ; ELECTRON-DEFICIENT ALKENES ; PROMOTED CLEAVAGE ; BOND FORMATION ; KETONES ; EFFICIENT ; ACID ; MERCAPTANS
英文摘要:

S-Alkylisothiouronium salt has been found to be a nontoxic, odorless and simply operational alternative of thiol for the thia-Michael addition with electron-deficient olefins. The reactions were carried out under alkaline conditions in water at room temperature within 5-20 minutes to afford the expected products in good to excellent yields.

语种: 英语
WOS记录号: WOS:000247832200010
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/55906
Appears in Collections:北京大学药学院_期刊论文

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作者单位: Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100083, Peoples R China

Recommended Citation:
Zhao, Yan,Ge, Ze-Mei,Cheng, Tie-Ming,et al. Thia-Michael addition using cheap and odorless S-alkylisothiouronium salts as thiol equivalents in water[J]. SYNLETT,2007(10):1529-1532.
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