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2-Pyridyl glycoside: an alternative glycosyl donor in preactivation protocol
Xiong, De-Cai; Yang, An-Qi; Yu, Yang; Ye, Xin-Shan
关键词2-pyridyl Glycoside Trifluoromethanesulfonic Anhydride Preactivation Glycosylation One-pot Synthesis
刊名TETRAHEDRON LETTERS
2015
DOI10.1016/j.tetlet.2014.11.066
56期:1页:211-214
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Organic
资助者Ministry of Science and Technology of China ; National Natural Science Foundation of China ; Beijing Natural Science Foundation ; Beijing Higher Education Young Elite Teacher Project ; Ministry of Science and Technology of China ; National Natural Science Foundation of China ; Beijing Natural Science Foundation ; Beijing Higher Education Young Elite Teacher Project
研究领域[WOS]Chemistry
关键词[WOS]ONE-POT SYNTHESIS ; ALPHA-SELECTIVE GLYCOSYLATIONS ; PRE-ACTIVATION PROTOCOL ; ANTIGEN GLOBO-H ; OLIGOSACCHARIDE SYNTHESIS ; STEREOSELECTIVE GLYCOSYLATIONS ; STRATEGY ; THIOGLYCOSIDES ; 2,6-DIDEOXYTHIOGLYCOSIDES ; GLYCOBIOLOGY
英文摘要

2-Pyridyl glycosides have been identified to be powerful glycosyl donors for the preactivation-based oligosaccharide synthesis. By using stoichiometric amount of Tf2O, the 2-pyridyl glycosides were pre-activated, which subsequently underwent glycosylation reactions smoothly to produce the coupled products in high yields. Furthermore, the 2-pyridyl glycosides were applied to the efficient oligosaccharide assembly by the preactivation-based one-pot oligosaccharide synthesis protocol. (C) 2014 Elsevier Ltd. All rights reserved.

语种英语
所属项目编号2012 CB822100 ; 2012ZX09502001-001 ; 2012AA021504 ; 21102008 ; 21232002 ; 2142015 ; YETP0063
资助者Ministry of Science and Technology of China ; National Natural Science Foundation of China ; Beijing Natural Science Foundation ; Beijing Higher Education Young Elite Teacher Project ; Ministry of Science and Technology of China ; National Natural Science Foundation of China ; Beijing Natural Science Foundation ; Beijing Higher Education Young Elite Teacher Project
WOS记录号WOS:000348259800042
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/56317
Collection北京大学药学院
作者单位Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
Recommended Citation
GB/T 7714
Xiong, De-Cai,Yang, An-Qi,Yu, Yang,et al. 2-Pyridyl glycoside: an alternative glycosyl donor in preactivation protocol[J]. TETRAHEDRON LETTERS,2015,56(1):211-214.
APA Xiong, De-Cai,Yang, An-Qi,Yu, Yang,&Ye, Xin-Shan.(2015).2-Pyridyl glycoside: an alternative glycosyl donor in preactivation protocol.TETRAHEDRON LETTERS,56(1),211-214.
MLA Xiong, De-Cai,et al."2-Pyridyl glycoside: an alternative glycosyl donor in preactivation protocol".TETRAHEDRON LETTERS 56.1(2015):211-214.
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