IR@PKUHSC  > 北京大学药学院
学科主题药学
Dipeptide-catalyzed direct asymmetric aldol reaction
Shi, LX; Sun, Q; Ge, ZM; Zhu, YQ; Cheng, TM; Li, RT
关键词Aldol Reaction Organocatalysis Enamine Catalysis Dipeptides
刊名SYNLETT
2004-10-01
DOI10.1055/s-2004-831324
12页:2215-2217
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]SMALL ORGANIC-MOLECULES ; PROLINE ; ALDEHYDES ; PEPTIDES ; AMINOCATALYSIS ; KETONES
英文摘要

(L)-H-Pro-(L)-Phe-OH (4) were found to be efficient catalysts for direct asymmetric aldol reactions between acetone and various aldehydes. The reaction conditions use a DMSO-NMM-PEMG 5000 system at 0 degreesC in high yields (62-96%) and enantioselectivities (up to >99% ee).

语种英语
WOS记录号WOS:000224374600040
Citation statistics
Cited Times:66[WOS]   [WOS Record]     [Related Records in WOS]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/56367
Collection北京大学药学院
作者单位Peking Univ, Sch Pharmaceut Sci, Beijing 100083, Peoples R China
Recommended Citation
GB/T 7714
Shi, LX,Sun, Q,Ge, ZM,et al. Dipeptide-catalyzed direct asymmetric aldol reaction[J]. SYNLETT,2004(12):2215-2217.
APA Shi, LX,Sun, Q,Ge, ZM,Zhu, YQ,Cheng, TM,&Li, RT.(2004).Dipeptide-catalyzed direct asymmetric aldol reaction.SYNLETT(12),2215-2217.
MLA Shi, LX,et al."Dipeptide-catalyzed direct asymmetric aldol reaction".SYNLETT .12(2004):2215-2217.
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