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学科主题: 药学
题名:
Dipeptide-catalyzed direct asymmetric aldol reaction
作者: Shi, LX; Sun, Q; Ge, ZM; Zhu, YQ; Cheng, TM; Li, RT
关键词: aldol reaction ; organocatalysis ; enamine catalysis ; dipeptides
刊名: SYNLETT
发表日期: 2004-10-01
DOI: 10.1055/s-2004-831324
期: 12, 页:2215-2217
收录类别: SCI ; IC ; CCR
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
关键词[WOS]: SMALL ORGANIC-MOLECULES ; PROLINE ; ALDEHYDES ; PEPTIDES ; AMINOCATALYSIS ; KETONES
英文摘要:

(L)-H-Pro-(L)-Phe-OH (4) were found to be efficient catalysts for direct asymmetric aldol reactions between acetone and various aldehydes. The reaction conditions use a DMSO-NMM-PEMG 5000 system at 0 degreesC in high yields (62-96%) and enantioselectivities (up to >99% ee).

语种: 英语
WOS记录号: WOS:000224374600040
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/56367
Appears in Collections:北京大学药学院_期刊论文

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作者单位: Peking Univ, Sch Pharmaceut Sci, Beijing 100083, Peoples R China

Recommended Citation:
Shi, LX,Sun, Q,Ge, ZM,et al. Dipeptide-catalyzed direct asymmetric aldol reaction[J]. SYNLETT,2004(12):2215-2217.
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