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学科主题: 药学
题名:
The synthesis of 2-deoxy-alpha-D-glycosides from D-glycals catalyzed by TMSI and PPh3
作者: Cui, Xi-Kai; Zhong, Ming; Meng, Xiang-Bao; Li, Zhong-Jun
关键词: 2-Deoxyglycoside ; Glycal ; TMSI ; alpha-Selective glycosylation
刊名: CARBOHYDRATE RESEARCH
发表日期: 2012-09-01
DOI: 10.1016/j.carres.2012.06.004
卷: 358, 页:19-22
收录类别: SCI ; IC ; CCR
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Biochemistry & Molecular Biology ; Chemistry, Applied ; Chemistry, Organic
研究领域[WOS]: Biochemistry & Molecular Biology ; Chemistry
关键词[WOS]: ALCOHOLS ; 2-DEOXY-ALPHA-GLYCOSIDES ; TETRAHYDROPYRANYLATION ; MECHANISMS
英文摘要:

2-Deoxyglycosides were synthesized in high alpha-selectivity by the direct addition of alcohols to D-glucal and D-galactal catalyzed by TMSI and PPh3. The acid labile isopropylidene group is tolerated under this condition. (C) 2012 Elsevier Ltd. All rights reserved.

语种: 英语
所属项目编号: 21072017 ; 2012CB822100
项目资助者: National Natural Science Foundation of China (NSFC) ; National Basic Research Program of China
WOS记录号: WOS:000307823200003
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/56578
Appears in Collections:北京大学药学院_化学生物学系_期刊论文

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作者单位: Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Dept Biol Chem, Beijing 100191, Peoples R China

Recommended Citation:
Cui, Xi-Kai,Zhong, Ming,Meng, Xiang-Bao,et al. The synthesis of 2-deoxy-alpha-D-glycosides from D-glycals catalyzed by TMSI and PPh3[J]. CARBOHYDRATE RESEARCH,2012,358:19-22.
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