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Synthesis of PVC-TEPA-Supported Proline Derivative and Its Catalytic Behavior in the Direct Asymmetric Aldol Reaction
Zou, Jun1,2; Zhao, Wenshan1,2; Li, Runtao3; Zhang, Hefeng1,2; Cui, Yuanchen1,2
关键词Organocatalysis Polymer-supported Catalyst Asymmetric Aldol Reaction Pvc-tepa Proline
刊名JOURNAL OF APPLIED POLYMER SCIENCE
2010-10-15
DOI10.1002/app.29892
118期:2页:1020-1026
收录类别SCI
文章类型Article
WOS标题词Science & Technology
类目[WOS]Polymer Science
研究领域[WOS]Polymer Science
关键词[WOS]ENANTIOSELECTIVE ALDOL ; WATER ; ALDEHYDES ; EFFICIENT ; HYDROGENATION
英文摘要

PVC-TEPA-supported L-proline catalyst has been synthesized and characterized by IR. It is developed as an efficient catalyst for the direct asymmetric aldol reaction of unmodified ketones with various aldehydes in the presence of water at 0 degrees C. The corresponding aldol products were obtained with high yields (up to 94%) and good enantioselectivities (up to 97% ee) on optimized conditions. Recycling investigations have shown that this material can be reused without loss of catalytic activity and stereoselectivity for at least 15 cycles. (C) 2010 Wiley Periodicals, Inc. J Appl Polym Sci 118: 1020-1026, 2010

语种英语
WOS记录号WOS:000280748400046
Citation statistics
Cited Times:11[WOS]   [WOS Record]     [Related Records in WOS]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/56714
Collection北京大学药学院
北京大学药学院_化学生物学系
作者单位1.Henan Univ, Coll Chem & Chem Engn, Kaifeng 475001, Peoples R China
2.Henan Univ, Inst Nat Prod & Med Chem, Kaifeng 475001, Peoples R China
3.Peking Univ, Sch Pharmaceut Sci, Beijing 100083, Peoples R China
Recommended Citation
GB/T 7714
Zou, Jun,Zhao, Wenshan,Li, Runtao,et al. Synthesis of PVC-TEPA-Supported Proline Derivative and Its Catalytic Behavior in the Direct Asymmetric Aldol Reaction[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2010,118(2):1020-1026.
APA Zou, Jun,Zhao, Wenshan,Li, Runtao,Zhang, Hefeng,&Cui, Yuanchen.(2010).Synthesis of PVC-TEPA-Supported Proline Derivative and Its Catalytic Behavior in the Direct Asymmetric Aldol Reaction.JOURNAL OF APPLIED POLYMER SCIENCE,118(2),1020-1026.
MLA Zou, Jun,et al."Synthesis of PVC-TEPA-Supported Proline Derivative and Its Catalytic Behavior in the Direct Asymmetric Aldol Reaction".JOURNAL OF APPLIED POLYMER SCIENCE 118.2(2010):1020-1026.
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