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学科主题: 药学
题名:
Highly Efficient C-H Hydroxylation of Carbonyl Compounds with Oxygen under Mild Conditions
作者: Liang, Yu-Feng1; Jiao, Ning1,2
关键词: cesium ; CH functionalization ; dioxygen ; hydroxylation ; oxygenation
刊名: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
发表日期: 2014-01-07
DOI: 10.1002/anie.201308698
卷: 53, 期:2, 页:548-552
收录类别: SCI ; IC ; CCR
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
关键词[WOS]: PALLADIUM-CATALYZED OXIDATION ; AEROBIC ALCOHOL OXIDATIONS ; MOLECULAR-OXYGEN ; ALPHA-HYDROXYLATION ; 1,3-DICARBONYL COMPOUNDS ; DIOXYGEN ACTIVATION ; ORGANIC-CHEMICALS ; HYDROGEN-PEROXIDE ; OXIDASE CATALYSIS ; ELECTRON-TRANSFER
英文摘要:

A transition-metal-free Cs2CO3-catalyzed -hydroxylation of carbonyl compounds with O-2 as the oxygen source is described. This reaction provides an efficient approach to tertiary -hydroxycarbonyl compounds, which are highly valued chemicals and widely used in the chemical and pharmaceutical industry. The simple conditions and the use of molecular oxygen as both the oxidant and the oxygen source make this protocol very environmentally friendly and practical. This transformation is highly efficient and highly selective for tertiary C(sp(3))H bond cleavage.

语种: 英语
所属项目编号: 2009CB825300 ; 21172006
项目资助者: National Basic Research Program of China (973 Program) ; National Science Foundation of China ; National Young Top-Notch Talent Support Program
WOS记录号: WOS:000329152600036
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/56860
Appears in Collections:北京大学药学院_期刊论文

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作者单位: 1.Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
2.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

Recommended Citation:
Liang, Yu-Feng,Jiao, Ning. Highly Efficient C-H Hydroxylation of Carbonyl Compounds with Oxygen under Mild Conditions[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2014,53(2):548-552.
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