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学科主题: 药学
题名:
Pre-activation protocol leading to highly stereoselectivity-controllable glycosylations of oxazolidinone protected glucosamines
作者: Geng, Yiqun; Zhang, Li-He; Ye, Xin-Shan
刊名: CHEMICAL COMMUNICATIONS
发表日期: 2008
DOI: 10.1039/b712591g
期: 5, 页:597-599
收录类别: SCI ; IC ; CCR
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
关键词[WOS]: OLIGOSACCHARIDE SYNTHESIS ; BETA-MANNOPYRANOSIDES ; SULFOXIDE METHOD ; HEPARIN ; STRATEGY ; THIOGLYCOSIDES ; STEREOCONTROL ; DERIVATIVES ; SUGARS ; DONOR
英文摘要:

Under pre-activation glycosylation conditions, the 4,6-di-O-acetyl-N- acetyloxazolidinone protected donor afforded either excellent beta- or alpha-stereoselectivity simply by means of the addition of hindered base TTBP or the absence of base, leading to the controllable stereochemistry of coupling reactions.

语种: 英语
WOS记录号: WOS:000252553300016
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/58282
Appears in Collections:北京大学药学院_期刊论文

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作者单位: Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100083, Peoples R China

Recommended Citation:
Geng, Yiqun,Zhang, Li-He,Ye, Xin-Shan. Pre-activation protocol leading to highly stereoselectivity-controllable glycosylations of oxazolidinone protected glucosamines[J]. CHEMICAL COMMUNICATIONS,2008(5):597-599.
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