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Iron-Facilitated Direct Oxidative C-H Transformation of Allylarenes or Alkenes to Alkenyl Nitriles
Qin, Chong1; Jiao, Ning1,2
刊名JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
2010-11-17
DOI10.1021/ja1070202
132期:45页:15893-15895
收录类别SCI ; CCR
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]ALLYLIC AMINATION ; ORGANIC-SYNTHESIS ; BOND FUNCTIONALIZATION ; SCHMIDT REACTION ; ALKYLATION ; ACTIVATION ; CATALYSIS ; AZIDES ; OLEFINS ; ARYL
英文摘要

This paper describes the first direct approach to alkenyl nitriles from allylarenes or alkenes facilitated by an inexpensive homogeneous iron catalyst. Three C-H bond cleavages occur under the mild conditions during this process. Mechanistic studies indicate that the cleavage of the allyl C(sp(3))-H bond is involved in the rate-determining step. This observation may provide an opportunity to achieve C(sp(3))-H functionalization catalyzed by an iron catalyst.

语种英语
WOS记录号WOS:000284202200020
项目编号20702002 ; 20872003 ; 2009CB825300
资助机构Peking University ; National Science Foundation of China ; National Basic Research Program of China (973 Program)
引用统计
被引频次:131[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/58367
专题北京大学药学院
北京大学药学院_天然药物与仿生药物国家重点实验室
作者单位1.Peking Univ, State Key Lab Nat & Biomimet Drugs, Sch Pharmaceut Sci, Beijing 100191, Peoples R China
2.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
推荐引用方式
GB/T 7714
Qin, Chong,Jiao, Ning. Iron-Facilitated Direct Oxidative C-H Transformation of Allylarenes or Alkenes to Alkenyl Nitriles[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2010,132(45):15893-15895.
APA Qin, Chong,&Jiao, Ning.(2010).Iron-Facilitated Direct Oxidative C-H Transformation of Allylarenes or Alkenes to Alkenyl Nitriles.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,132(45),15893-15895.
MLA Qin, Chong,et al."Iron-Facilitated Direct Oxidative C-H Transformation of Allylarenes or Alkenes to Alkenyl Nitriles".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 132.45(2010):15893-15895.
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