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学科主题: 药学
题名:
Iron-Facilitated Direct Oxidative C-H Transformation of Allylarenes or Alkenes to Alkenyl Nitriles
作者: Qin, Chong1; Jiao, Ning1,2
刊名: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
发表日期: 2010-11-17
DOI: 10.1021/ja1070202
卷: 132, 期:45, 页:15893-15895
收录类别: SCI ; CCR
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
关键词[WOS]: ALLYLIC AMINATION ; ORGANIC-SYNTHESIS ; BOND FUNCTIONALIZATION ; SCHMIDT REACTION ; ALKYLATION ; ACTIVATION ; CATALYSIS ; AZIDES ; OLEFINS ; ARYL
英文摘要:

This paper describes the first direct approach to alkenyl nitriles from allylarenes or alkenes facilitated by an inexpensive homogeneous iron catalyst. Three C-H bond cleavages occur under the mild conditions during this process. Mechanistic studies indicate that the cleavage of the allyl C(sp(3))-H bond is involved in the rate-determining step. This observation may provide an opportunity to achieve C(sp(3))-H functionalization catalyzed by an iron catalyst.

语种: 英语
所属项目编号: 20702002 ; 20872003 ; 2009CB825300
项目资助者: Peking University ; National Science Foundation of China ; National Basic Research Program of China (973 Program)
WOS记录号: WOS:000284202200020
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/58367
Appears in Collections:北京大学药学院_期刊论文

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作者单位: 1.Peking Univ, State Key Lab Nat & Biomimet Drugs, Sch Pharmaceut Sci, Beijing 100191, Peoples R China
2.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

Recommended Citation:
Qin, Chong,Jiao, Ning. Iron-Facilitated Direct Oxidative C-H Transformation of Allylarenes or Alkenes to Alkenyl Nitriles[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2010,132(45):15893-15895.
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