IR@PKUHSC  > 北京大学药学院
学科主题药学
Additive-controlled stereoselective glycosylations of 2,3-oxazolidinone protected glucosamine or galactosamine thioglycoside donors with phenols based on preactivation protocol
Qin, Qi; Xiong, De-Cai; Ye, Xin-Shan
关键词Additive Stereoselectivity Glycosylation Preactivation Aryl glycoside
刊名CARBOHYDRATE RESEARCH
2015-02-11
DOI10.1016/j.carres.2014.07.004
403页:104-114
收录类别SCI ; IC
文章类型Article
WOS标题词Science & Technology
类目[WOS]Biochemistry & Molecular Biology ; Chemistry, Applied ; Chemistry, Organic
资助者Ministry of Science and Technology of China ; National Natural Science Foundation of China ; Beijing Natural Science Foundation ; Beijing Higher Education Young Elite Teacher Project ; Ministry of Science and Technology of China ; National Natural Science Foundation of China ; Beijing Natural Science Foundation ; Beijing Higher Education Young Elite Teacher Project
研究领域[WOS]Biochemistry & Molecular Biology ; Chemistry
关键词[WOS]NEIGHBORING GROUP PARTICIPATION ; HEPARIN-LIKE OLIGOSACCHARIDES ; ONE-POT SYNTHESIS ; BETA-MANNOPYRANOSIDES ; O-GLCNAC ; GLYCOCINNASPERIMICIN-D ; GLYCOSIDIC LINKAGES ; ALPHA-GLYCOSYLATION ; ENDOCYCLIC CLEAVAGE ; SULFOXIDE METHOD
英文摘要

Stereo-controllable glycosylation reactions of 2,3-oxazolidinone protected glucosamine thioglycoside donor with different phenol acceptors based on preactivation protocol, are described. It was found that BF3.Et2O worked as alpha-directing additive, while TTBP acted as beta-directing additive. Simply by altering additives, either alpha-aryl glycosides or beta-aryl glycosides were achieved in a stereoselective manner. The additives were also applied to the stereoselective glycosylation reactions of 2,3-oxazolidinone protected galactosamine donor with phenol substrates. (C) 2014 Elsevier Ltd. All rights reserved.

语种英语
所属项目编号2012CB822100 ; 2013CB910700 ; 2012ZX09502001-001 ; 21232002 ; 2142015 ; YETP0063
资助者Ministry of Science and Technology of China ; National Natural Science Foundation of China ; Beijing Natural Science Foundation ; Beijing Higher Education Young Elite Teacher Project ; Ministry of Science and Technology of China ; National Natural Science Foundation of China ; Beijing Natural Science Foundation ; Beijing Higher Education Young Elite Teacher Project
WOS记录号WOS:000349085900013
Citation statistics
Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/58410
Collection北京大学药学院
作者单位Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
Recommended Citation
GB/T 7714
Qin, Qi,Xiong, De-Cai,Ye, Xin-Shan. Additive-controlled stereoselective glycosylations of 2,3-oxazolidinone protected glucosamine or galactosamine thioglycoside donors with phenols based on preactivation protocol[J]. CARBOHYDRATE RESEARCH,2015,403:104-114.
APA Qin, Qi,Xiong, De-Cai,&Ye, Xin-Shan.(2015).Additive-controlled stereoselective glycosylations of 2,3-oxazolidinone protected glucosamine or galactosamine thioglycoside donors with phenols based on preactivation protocol.CARBOHYDRATE RESEARCH,403,104-114.
MLA Qin, Qi,et al."Additive-controlled stereoselective glycosylations of 2,3-oxazolidinone protected glucosamine or galactosamine thioglycoside donors with phenols based on preactivation protocol".CARBOHYDRATE RESEARCH 403(2015):104-114.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
谷歌学术
谷歌学术Similar articles in
[Qin, Qi]'s Articles
[Xiong, De-Cai]'s Articles
[Ye, Xin-Shan]'s Articles
百度学术
百度学术Similar articles in
[Qin, Qi]'s Articles
[Xiong, De-Cai]'s Articles
[Ye, Xin-Shan]'s Articles
必应学术
必应学术Similar articles in
[Qin, Qi]'s Articles
[Xiong, De-Cai]'s Articles
[Ye, Xin-Shan]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.