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学科主题: 药学
题名:
A metal-free synthesis of oxindoles by a radical addition-cyclization onto N-arylacrylamides with xanthates
作者: Wang, Shucheng; Huang, Xuhu; Li, Bowen; Ge, Zemei; Wang, Xin; Li, Runtao
关键词: Oxindoles ; Metal free ; Alkenes ; Xanthates ; Radical
刊名: TETRAHEDRON
发表日期: 2015-03-25
DOI: 10.1016/j.tet.2015.01.049
卷: 71, 期:12, 页:1869-1875
收录类别: SCI ; IC ; CCR
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
关键词[WOS]: CATALYZED OXIDATIVE ARYLALKYLATION ; ASYMMETRIC-SYNTHESIS ; ACTIVATED ALKENES ; ORGANIC-SYNTHESIS ; QUATERNARY CENTERS ; EFFICIENT ROUTE ; BOND-CLEAVAGE ; PHYSOSTIGMINE ; CONSTRUCTION ; SUBSTITUTION
英文摘要:

A convenient, high yielding synthesis of oxindoles by metal-free di-functionalization of alkenes with xanthates has been developed. This transformation involves a radical addition/cyclization process. Various arylalkylation products including alkyl ester-, benzyl-, cyano-, ketone-, amine-, and amide-substituted oxindoles were prepared in good to excellent yields. (C) 2015 Elsevier Ltd. All rights reserved.

语种: 英语
所属项目编号: 81172915
项目资助者: National Natural Science Foundation of China
WOS记录号: WOS:000350835800013
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/58448
Appears in Collections:北京大学药学院_期刊论文

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作者单位: Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China

Recommended Citation:
Wang, Shucheng,Huang, Xuhu,Li, Bowen,et al. A metal-free synthesis of oxindoles by a radical addition-cyclization onto N-arylacrylamides with xanthates[J]. TETRAHEDRON,2015,71(12):1869-1875.
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