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A metal-free synthesis of oxindoles by a radical addition-cyclization onto N-arylacrylamides with xanthates
Wang, Shucheng; Huang, Xuhu; Li, Bowen; Ge, Zemei; Wang, Xin; Li, Runtao
关键词Oxindoles Metal free Alkenes Xanthates Radical
刊名TETRAHEDRON
2015-03-25
DOI10.1016/j.tet.2015.01.049
71期:12页:1869-1875
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]CATALYZED OXIDATIVE ARYLALKYLATION ; ASYMMETRIC-SYNTHESIS ; ACTIVATED ALKENES ; ORGANIC-SYNTHESIS ; QUATERNARY CENTERS ; EFFICIENT ROUTE ; BOND-CLEAVAGE ; PHYSOSTIGMINE ; CONSTRUCTION ; SUBSTITUTION
英文摘要

A convenient, high yielding synthesis of oxindoles by metal-free di-functionalization of alkenes with xanthates has been developed. This transformation involves a radical addition/cyclization process. Various arylalkylation products including alkyl ester-, benzyl-, cyano-, ketone-, amine-, and amide-substituted oxindoles were prepared in good to excellent yields. (C) 2015 Elsevier Ltd. All rights reserved.

语种英语
WOS记录号WOS:000350835800013
项目编号81172915
资助机构National Natural Science Foundation of China
引用统计
被引频次:11[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/58448
专题北京大学药学院
北京大学药学院_化学生物学系
作者单位Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
推荐引用方式
GB/T 7714
Wang, Shucheng,Huang, Xuhu,Li, Bowen,et al. A metal-free synthesis of oxindoles by a radical addition-cyclization onto N-arylacrylamides with xanthates[J]. TETRAHEDRON,2015,71(12):1869-1875.
APA Wang, Shucheng,Huang, Xuhu,Li, Bowen,Ge, Zemei,Wang, Xin,&Li, Runtao.(2015).A metal-free synthesis of oxindoles by a radical addition-cyclization onto N-arylacrylamides with xanthates.TETRAHEDRON,71(12),1869-1875.
MLA Wang, Shucheng,et al."A metal-free synthesis of oxindoles by a radical addition-cyclization onto N-arylacrylamides with xanthates".TETRAHEDRON 71.12(2015):1869-1875.
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