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Organocatalytic Asymmetric Intermolecular Dehydrogenative alpha-Alkylation of Aldehydes Using Molecular Oxygen as Oxidant
Zhang, Bo1; Xiang, Shi-Kai1; Zhang, Li-He1; Cui, Yuxin1; Jiao, Ning1,2
刊名ORGANIC LETTERS
2011-10-07
DOI10.1021/ol202090a
13期:19页:5212-5215
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]BRONSTED-ACID CATALYSIS ; C-H BONDS ; ENAMINE CATALYSIS ; ENANTIOSELECTIVE CYCLOPROPANATION ; COUPLING REACTION ; PHASE-TRANSFER ; AMINO-ACIDS ; ACTIVATION ; OXIDATION ; ALCOHOLS
英文摘要

An organocatalytic enantioselective intermolecular oxidative dehydrogenative alpha-alkylation of aldehydes via benzylic C-H bond activation has been developed. The asymmetric reaction is smoothly fulfilled by using simple and green molecular oxygen as the oxidant. Two hydrogen dissociations make this transformation more environmentally benign because of high atom efficiency.

语种英语
WOS记录号WOS:000295313900060
项目编号20872003 ; 2009CB825300
资助机构Peking University ; National Science Foundation of China ; National Basic Research Program of China (973 Program)
引用统计
被引频次:71[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/58645
专题北京大学药学院
北京大学药学院_天然药物与仿生药物国家重点实验室
北京大学药学院_药物化学系
作者单位1.Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
2.E China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Bo,Xiang, Shi-Kai,Zhang, Li-He,et al. Organocatalytic Asymmetric Intermolecular Dehydrogenative alpha-Alkylation of Aldehydes Using Molecular Oxygen as Oxidant[J]. ORGANIC LETTERS,2011,13(19):5212-5215.
APA Zhang, Bo,Xiang, Shi-Kai,Zhang, Li-He,Cui, Yuxin,&Jiao, Ning.(2011).Organocatalytic Asymmetric Intermolecular Dehydrogenative alpha-Alkylation of Aldehydes Using Molecular Oxygen as Oxidant.ORGANIC LETTERS,13(19),5212-5215.
MLA Zhang, Bo,et al."Organocatalytic Asymmetric Intermolecular Dehydrogenative alpha-Alkylation of Aldehydes Using Molecular Oxygen as Oxidant".ORGANIC LETTERS 13.19(2011):5212-5215.
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