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学科主题: 药学
题名:
Organocatalytic Asymmetric Intermolecular Dehydrogenative alpha-Alkylation of Aldehydes Using Molecular Oxygen as Oxidant
作者: Zhang, Bo1; Xiang, Shi-Kai1; Zhang, Li-He1; Cui, Yuxin1; Jiao, Ning1,2
刊名: ORGANIC LETTERS
发表日期: 2011-10-07
DOI: 10.1021/ol202090a
卷: 13, 期:19, 页:5212-5215
收录类别: SCI ; IC ; CCR
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
关键词[WOS]: BRONSTED-ACID CATALYSIS ; C-H BONDS ; ENAMINE CATALYSIS ; ENANTIOSELECTIVE CYCLOPROPANATION ; COUPLING REACTION ; PHASE-TRANSFER ; AMINO-ACIDS ; ACTIVATION ; OXIDATION ; ALCOHOLS
英文摘要:

An organocatalytic enantioselective intermolecular oxidative dehydrogenative alpha-alkylation of aldehydes via benzylic C-H bond activation has been developed. The asymmetric reaction is smoothly fulfilled by using simple and green molecular oxygen as the oxidant. Two hydrogen dissociations make this transformation more environmentally benign because of high atom efficiency.

语种: 英语
所属项目编号: 20872003 ; 2009CB825300
项目资助者: Peking University ; National Science Foundation of China ; National Basic Research Program of China (973 Program)
WOS记录号: WOS:000295313900060
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/58645
Appears in Collections:北京大学药学院_期刊论文

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作者单位: 1.Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
2.E China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China

Recommended Citation:
Zhang, Bo,Xiang, Shi-Kai,Zhang, Li-He,et al. Organocatalytic Asymmetric Intermolecular Dehydrogenative alpha-Alkylation of Aldehydes Using Molecular Oxygen as Oxidant[J]. ORGANIC LETTERS,2011,13(19):5212-5215.
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