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学科主题: 药学
题名:
Metal-Free, Organocatalytic Syn Diacetoxylation of Alkenes
作者: Zhong, Wenhe; Liu, Shan; Yang, Jun; Meng, Xiangbao; Li, Zhongjun
刊名: ORGANIC LETTERS
发表日期: 2012-07-06
DOI: 10.1021/ol301311e
卷: 14, 期:13, 页:3336-3339
收录类别: SCI ; IC ; CCR
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
关键词[WOS]: M-CHLOROPERBENZOIC ACID ; OLEFIN CIS-DIHYDROXYLATION ; IN-SITU GENERATION ; ASYMMETRIC DIHYDROXYLATION ; CATALYZED DIHYDROXYLATION ; PHENOL DEAROMATIZATION ; ALPHA-ACETOXYLATION ; OXIDATIVE CLEAVAGE ; HYDROGEN-PEROXIDE ; MOLECULAR-OXYGEN
英文摘要:

A novel method for the organocatalytic syn diacetoxylation of alkenes has been developed using aryl iodides as efficient catalysts. A broad range of substrates, including electron-rich as well as electron-deficient alkenes, are smoothly transformed by the new procedure, furnishing the desired products in good to excellent yields with high diastereoselectivity (up to >19:1 dr).

语种: 英语
所属项目编号: 21072017 ; 20732001 ; 2012CB822100
项目资助者: National Natural Science Foundation of China (NSFC) ; National Basic Research Program of China
WOS记录号: WOS:000306050300026
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/59057
Appears in Collections:北京大学药学院_化学生物学系_期刊论文

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作者单位: Peking Univ, Dept Biol Chem, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China

Recommended Citation:
Zhong, Wenhe,Liu, Shan,Yang, Jun,et al. Metal-Free, Organocatalytic Syn Diacetoxylation of Alkenes[J]. ORGANIC LETTERS,2012,14(13):3336-3339.
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