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学科主题: 药学
题名:
Unexpected synthesis of 1,3,5-triarly-1,5-diketones from aryl ketones via di-enamine mechanism
作者: Liu, Bin1; Wang, Junfeng2; Pang, Yi2; Ge, Zemei1; Li, Runtao1
关键词: Aromatic aldehyde ; Aryl ketone ; Synthesis ; 1,3,5-Triaryl-1,5-diketones ; Di-enamine mechanism
刊名: TETRAHEDRON
发表日期: 2014-12-02
DOI: 10.1016/j.tet.2014.10.009
卷: 70, 期:48, 页:9240-9244
收录类别: SCI ; IC ; CCR
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
关键词[WOS]: CONJUGATE ADDITION-REACTIONS ; ASYMMETRIC MICHAEL ADDITION ; SILYL ENOL ETHERS ; CATALYSIS ; ALDEHYDES ; PATHWAY ; ACID
英文摘要:

An unexpected reaction of aryl ketone with acetohydrazone of aromatic aldehyde via 1,2-di-enamine/diiminium mechanism was discovered, leading to efficient synthesis of 1,3,5-triaryl-1,5-diketones in good to excellent yields. (C) 2014 Elsevier Ltd. All rights reserved.

语种: 英语
所属项目编号: 20972005 ; 81172915
项目资助者: National Natural Science Foundation of China
WOS记录号: WOS:000345492200010
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/59231
Appears in Collections:北京大学药学院_期刊论文

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作者单位: 1.Univ Akron, Dept Chem, Akron, OH 44325 USA
2.Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China

Recommended Citation:
Liu, Bin,Wang, Junfeng,Pang, Yi,et al. Unexpected synthesis of 1,3,5-triarly-1,5-diketones from aryl ketones via di-enamine mechanism[J]. TETRAHEDRON,2014,70(48):9240-9244.
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