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学科主题: 药学
题名:
Copper-Catalyzed C-H Azidation of Anilines under Mild Conditions
作者: Tang, Conghui1; Jiao, Ning1,2
刊名: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
发表日期: 2012-11-21
DOI: 10.1021/ja3089907
卷: 134, 期:46, 页:18924-18927
收录类别: SCI ; IC ; CCR
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
关键词[WOS]: ARYL AZIDES ; DIRECTING GROUP ; BOND ACTIVATION ; COMBINATION REACTIONS ; ULLMANN CONDENSATION ; AMINATION REACTIONS ; COUPLING REACTIONS ; CARBOXYLIC-ACIDS ; FACILE SYNTHESIS ; AROMATIC-AMINES
英文摘要:

A novel and efficient copper-catalyzed azidation reaction of anilines via C-H activation has been developed. This method, in which the primary amine acts as a directing group by coordinating to the metal center, provides ortho azidation products regioselectively under mild conditions. This effective route for the synthesis of aryl azides is of great significance in view of the versatile reactivity of the azide products.

语种: 英语
所属项目编号: 2009CB825300 ; 21172006
项目资助者: National Basic Research Program of China (973 Program) ; National Science Foundation of China
WOS记录号: WOS:000311324900012
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/59347
Appears in Collections:北京大学药学院_期刊论文

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作者单位: 1.Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
2.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

Recommended Citation:
Tang, Conghui,Jiao, Ning. Copper-Catalyzed C-H Azidation of Anilines under Mild Conditions[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2012,134(46):18924-18927.
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