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Copper-Catalyzed C-H Azidation of Anilines under Mild Conditions
Tang, Conghui1; Jiao, Ning1,2
刊名JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
2012-11-21
DOI10.1021/ja3089907
134期:46页:18924-18927
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]ARYL AZIDES ; DIRECTING GROUP ; BOND ACTIVATION ; COMBINATION REACTIONS ; ULLMANN CONDENSATION ; AMINATION REACTIONS ; COUPLING REACTIONS ; CARBOXYLIC-ACIDS ; FACILE SYNTHESIS ; AROMATIC-AMINES
英文摘要

A novel and efficient copper-catalyzed azidation reaction of anilines via C-H activation has been developed. This method, in which the primary amine acts as a directing group by coordinating to the metal center, provides ortho azidation products regioselectively under mild conditions. This effective route for the synthesis of aryl azides is of great significance in view of the versatile reactivity of the azide products.

语种英语
WOS记录号WOS:000311324900012
项目编号2009CB825300 ; 21172006
资助机构National Basic Research Program of China (973 Program) ; National Science Foundation of China
引用统计
被引频次:155[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/59347
专题北京大学药学院
北京大学药学院_天然药物与仿生药物国家重点实验室
作者单位1.Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
2.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
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Tang, Conghui,Jiao, Ning. Copper-Catalyzed C-H Azidation of Anilines under Mild Conditions[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2012,134(46):18924-18927.
APA Tang, Conghui,&Jiao, Ning.(2012).Copper-Catalyzed C-H Azidation of Anilines under Mild Conditions.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,134(46),18924-18927.
MLA Tang, Conghui,et al."Copper-Catalyzed C-H Azidation of Anilines under Mild Conditions".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 134.46(2012):18924-18927.
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