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An Efficient Transformation from Benzyl or Allyl Halides to Aryl and Alkenyl Nitriles
Zhou, Wang1; Xu, Jiaojiao1; Zhang, Liangren1; Jiao, Ning1,2
刊名ORGANIC LETTERS
2010-06-18
DOI10.1021/ol101094u
12期:12页:2888-2891
收录类别SCI ; CCR
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]PALLADIUM-CATALYZED CYANATION ; DIRECT OXIDATIVE CONVERSION ; SCHMIDT REACTION ; AQUEOUS AMMONIA ; PRIMARY AMIDES ; ALDEHYDE N,N-DIMETHYLHYDRAZONES ; HETEROGENEOUS CATALYST ; MOLECULAR-IODINE ; CATION-PI ; BROMIDES
英文摘要

A novel approach to aryl or alkenyl nitriles from benzyl and allyl halides has been developed. A tandem TBAB-catalyzed substitution and the subsequent novel oxidative rearrangement are involved in this transformation. To the best of our knowledge, this is the first transformation from allyl halides to alkenyl nitriles. The broad reaction scope and the mild conditions may make these methods of use in organic synthesis.

语种英语
WOS记录号WOS:000278616800054
项目编号20702002 ; 20872003 ; 2009CB825300
资助机构Peking University ; National Science Foundation of China ; National Basic Research Program of China (973 Program) ; Program for "NCET"
引用统计
被引频次:83[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/59376
专题北京大学药学院
北京大学药学院_天然药物与仿生药物国家重点实验室
北京大学药学院_药物化学系
作者单位1.Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
2.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
推荐引用方式
GB/T 7714
Zhou, Wang,Xu, Jiaojiao,Zhang, Liangren,et al. An Efficient Transformation from Benzyl or Allyl Halides to Aryl and Alkenyl Nitriles[J]. ORGANIC LETTERS,2010,12(12):2888-2891.
APA Zhou, Wang,Xu, Jiaojiao,Zhang, Liangren,&Jiao, Ning.(2010).An Efficient Transformation from Benzyl or Allyl Halides to Aryl and Alkenyl Nitriles.ORGANIC LETTERS,12(12),2888-2891.
MLA Zhou, Wang,et al."An Efficient Transformation from Benzyl or Allyl Halides to Aryl and Alkenyl Nitriles".ORGANIC LETTERS 12.12(2010):2888-2891.
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