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学科主题: 药学
题名:
Cu-mediated C-H cyanation of arenes using N,N-dimethylformamide (DMF) as the "CN" source
作者: Yan, Yuepeng1; Yuan, Yizhi1; Jiao, Ning1,2
刊名: Organic Chemistry Frontiers
发表日期: 2014
DOI: 10.1039/c4qo00205a
卷: 1, 期:10, 页:1176-1179
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
关键词[WOS]: PALLADIUM-CATALYZED CYANATION ; ARYL HALIDES ; CYANIDE SOURCE ; BOND-CLEAVAGE ; AMMONIUM IODIDE ; HETEROGENEOUS CATALYST ; OXIDATIVE CYANATION ; ORGANIC-SYNTHESIS ; ALKENYL NITRILES ; PRIMARY AMIDES
英文摘要:

This paper describes the direct C-H bond cyanation of 2-phenylpyridines employing N, N-dimethylformamide (DMF) as both the reagent and solvent. DMF provides both the C and N units in the generated "CN" group in this cyanation transformation. This reaction gives a novel protocol with high atom economy to extend the application of DMF and provides an alternative approach to aryl nitriles.

语种: 英语
所属项目编号: 21325206 ; 21172006 ; 20120001110013
项目资助者: National Science Foundation of China ; National Young Topnotch Talent Support Program ; PhD. Programs Foundation of the Ministry of Education of China
WOS记录号: WOS:000364430800007
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/59568
Appears in Collections:北京大学药学院_期刊论文

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作者单位: 1.Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
2.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

Recommended Citation:
Yan, Yuepeng,Yuan, Yizhi,Jiao, Ning. Cu-mediated C-H cyanation of arenes using N,N-dimethylformamide (DMF) as the "CN" source[J]. Organic Chemistry Frontiers,2014,1(10):1176-1179.
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