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Cu-mediated C-H cyanation of arenes using N,N-dimethylformamide (DMF) as the "CN" source
Yan, Yuepeng1; Yuan, Yizhi1; Jiao, Ning1,2
刊名Organic Chemistry Frontiers
2014
DOI10.1039/c4qo00205a
1期:10页:1176-1179
收录类别SCI
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]PALLADIUM-CATALYZED CYANATION ; ARYL HALIDES ; CYANIDE SOURCE ; BOND-CLEAVAGE ; AMMONIUM IODIDE ; HETEROGENEOUS CATALYST ; OXIDATIVE CYANATION ; ORGANIC-SYNTHESIS ; ALKENYL NITRILES ; PRIMARY AMIDES
英文摘要

This paper describes the direct C-H bond cyanation of 2-phenylpyridines employing N, N-dimethylformamide (DMF) as both the reagent and solvent. DMF provides both the C and N units in the generated "CN" group in this cyanation transformation. This reaction gives a novel protocol with high atom economy to extend the application of DMF and provides an alternative approach to aryl nitriles.

语种英语
WOS记录号WOS:000364430800007
引用统计
被引频次:21[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/59568
专题北京大学药学院
北京大学药学院_天然药物与仿生药物国家重点实验室
作者单位1.Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
2.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
推荐引用方式
GB/T 7714
Yan, Yuepeng,Yuan, Yizhi,Jiao, Ning. Cu-mediated C-H cyanation of arenes using N,N-dimethylformamide (DMF) as the "CN" source[J]. Organic Chemistry Frontiers,2014,1(10):1176-1179.
APA Yan, Yuepeng,Yuan, Yizhi,&Jiao, Ning.(2014).Cu-mediated C-H cyanation of arenes using N,N-dimethylformamide (DMF) as the "CN" source.Organic Chemistry Frontiers,1(10),1176-1179.
MLA Yan, Yuepeng,et al."Cu-mediated C-H cyanation of arenes using N,N-dimethylformamide (DMF) as the "CN" source".Organic Chemistry Frontiers 1.10(2014):1176-1179.
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