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学科主题: 药学
题名:
Total Synthesis of (-)-5,6-Dihydrocineromycin B
作者: Li, Guozhi1; Yang, Xiaoxia1; Zhai, Hongbin1,2
刊名: JOURNAL OF ORGANIC CHEMISTRY
发表日期: 2009-02-06
DOI: 10.1021/jo802503x
卷: 74, 期:3, 页:1356-1359
收录类别: SCI ; IC ; CCR
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
关键词[WOS]: ENANTIOSELECTIVE TOTAL-SYNTHESIS ; NATURAL-PRODUCTS ; REDUCTION ; ALCOHOLS
英文摘要:

An asymmetric total synthesis of (-)-5,6-dihydrocineromycin B has been accomplished in 13 steps from (-)-linalool O-triethylsilyl ether or 12 steps from geraniol. The present synthesis features (i) an intermolecular Wittig reaction involving an aldehyde possessing a ketophosphonate functionality and (ii) an intramolecular Horner-Wadsworth-Emmons olefination.

语种: 英语
所属项目编号: 90713007 ; 20772141 ; 20625204 ; 20632030 ; 2006AA09Z405 ; 2006AA09Z446
项目资助者: NSFC ; MOST_863
WOS记录号: WOS:000263004300054
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/59753
Appears in Collections:北京大学药学院_期刊论文

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作者单位: 1.Chinese Acad Sci, Shanghai Inst Organ Chem, Lab Modern Synthet Organ Chem, Shanghai 200032, Peoples R China
2.Peking Univ, State Key Lab Nat & Biomimet Drugs, Sch Pharmaceut Sci, Beijing 100083, Peoples R China

Recommended Citation:
Li, Guozhi,Yang, Xiaoxia,Zhai, Hongbin. Total Synthesis of (-)-5,6-Dihydrocineromycin B[J]. JOURNAL OF ORGANIC CHEMISTRY,2009,74(3):1356-1359.
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