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Synthesis of L-glucose and L-galactose derivatives from D-sugars
Xia, Tian-Yu; Li, Yang-Bing; Yin, Zhao-Jun; Meng, Xiang-Bao; Li, Shu-Chun; Li, Zhong-Jun
关键词Carbohydrates L-Hexoses Head-to-tail inversions Oxidation Decarboxylation One-pot Procedure
刊名CHINESE CHEMICAL LETTERS
2014-09-01
DOI10.1016/j.cclet.2014.06.007
25期:9页:1220-1224
收录类别SCI ; CCR
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]ENANTIOSELECTIVE DIHYDROXYLATION REACTIONS ; CHIRAL BUILDING-BLOCK ; L-HEXOSES ; L-MANNOSE ; ASYMMETRIC-SYNTHESIS ; HEPARAN-SULFATE ; SCALE SYNTHESIS ; EASY ACCESS ; L-GULOSE ; ROUTE
英文摘要

An efficient route to prepare L-glucose and L-galactose is described. The L-sugars are achieved by using the strategy of switching the functional groups at C1 and C5 of D-glucose and D-mannose. The oxidation and reduction of the silyl enol ether at C1 and the lead(IV) tetraacetate mediated oxidative decarboxylation at C5 are the key steps. L-Glucose and L-galactose are prepared in a convenient and inexpensive way. (C) 2014 Shu-Chun Li and Zhong-Jun Li. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

语种英语
WOS记录号WOS:000345880500003
项目编号2012CB822100 ; 2012ZX09502001-001 ; 20972012 ; 21232002
资助机构National Basic Research Program of China (973 Program) ; National Key Technology R&amp ; D Program "New Drug Innovation" of China ; National Natural Science Foundation of China
引用统计
被引频次:5[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/59949
专题北京大学药学院
北京大学药学院_化学生物学系
作者单位Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
推荐引用方式
GB/T 7714
Xia, Tian-Yu,Li, Yang-Bing,Yin, Zhao-Jun,et al. Synthesis of L-glucose and L-galactose derivatives from D-sugars[J]. CHINESE CHEMICAL LETTERS,2014,25(9):1220-1224.
APA Xia, Tian-Yu,Li, Yang-Bing,Yin, Zhao-Jun,Meng, Xiang-Bao,Li, Shu-Chun,&Li, Zhong-Jun.(2014).Synthesis of L-glucose and L-galactose derivatives from D-sugars.CHINESE CHEMICAL LETTERS,25(9),1220-1224.
MLA Xia, Tian-Yu,et al."Synthesis of L-glucose and L-galactose derivatives from D-sugars".CHINESE CHEMICAL LETTERS 25.9(2014):1220-1224.
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