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学科主题: 药学
题名:
Synthesis of L-glucose and L-galactose derivatives from D-sugars
作者: Xia, Tian-Yu; Li, Yang-Bing; Yin, Zhao-Jun; Meng, Xiang-Bao; Li, Shu-Chun; Li, Zhong-Jun
关键词: Carbohydrates ; L-Hexoses ; Head-to-tail inversions ; Oxidation ; Decarboxylation ; One-pot procedure
刊名: CHINESE CHEMICAL LETTERS
发表日期: 2014-09-01
DOI: 10.1016/j.cclet.2014.06.007
卷: 25, 期:9, 页:1220-1224
收录类别: SCI ; CCR
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
关键词[WOS]: ENANTIOSELECTIVE DIHYDROXYLATION REACTIONS ; CHIRAL BUILDING-BLOCK ; L-HEXOSES ; L-MANNOSE ; ASYMMETRIC-SYNTHESIS ; HEPARAN-SULFATE ; SCALE SYNTHESIS ; EASY ACCESS ; L-GULOSE ; ROUTE
英文摘要:

An efficient route to prepare L-glucose and L-galactose is described. The L-sugars are achieved by using the strategy of switching the functional groups at C1 and C5 of D-glucose and D-mannose. The oxidation and reduction of the silyl enol ether at C1 and the lead(IV) tetraacetate mediated oxidative decarboxylation at C5 are the key steps. L-Glucose and L-galactose are prepared in a convenient and inexpensive way. (C) 2014 Shu-Chun Li and Zhong-Jun Li. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

语种: 英语
所属项目编号: 2012CB822100 ; 2012ZX09502001-001 ; 20972012 ; 21232002
项目资助者: National Basic Research Program of China (973 Program) ; National Key Technology R&amp ; D Program "New Drug Innovation" of China ; National Natural Science Foundation of China
WOS记录号: WOS:000345880500003
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/59949
Appears in Collections:北京大学药学院_期刊论文

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作者单位: Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China

Recommended Citation:
Xia, Tian-Yu,Li, Yang-Bing,Yin, Zhao-Jun,et al. Synthesis of L-glucose and L-galactose derivatives from D-sugars[J]. CHINESE CHEMICAL LETTERS,2014,25(9):1220-1224.
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