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学科主题: 药学
题名:
A Cu-catalyzed practical approach to alpha-ketoesters under air: an efficient aerobic oxidative dehydrogenative coupling of alcohols and a-carbonyl aldehydes
作者: Zhang, Chun1; Jiao, Ning1,2
刊名: Organic Chemistry Frontiers
发表日期: 2014
DOI: 10.1039/c3qo00041a
卷: 1, 期:1, 页:109-112
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
关键词[WOS]: MOLECULAR-OXYGEN ; SELECTIVE OXIDATION ; SIALIC-ACID ; ESTERIFICATION ; ESTERS ; OXIDANT ; BOND ; FUNCTIONALIZATION ; REARRANGEMENT ; INHIBITORS
英文摘要:

A novel and efficient approach to alpha-ketoesters has been developed with wide functional group tolerance. This copper-catalyzed oxidative dehydrogenative coupling reaction of alcohols and alpha-carbonyl aldehydes employs air as the oxidant and generates H2O as the only by-product. Broad substrate scope, high atom economy and mild reaction conditions make this chemistry very practical.

语种: 英语
所属项目编号: 21325206 ; 21172006 ; 20120001110013
项目资助者: National Science Foundation of China ; National Young Top-notch Talent Support Program ; Ph.D. Programs Foundation of the Ministry of Education of China
WOS记录号: WOS:000364422700016
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/60024
Appears in Collections:北京大学药学院_期刊论文

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作者单位: 1.Peking Univ, State Key Lab Nat & Biomimet Drugs, Sch Pharmaceut Sci, Beijing 100191, Peoples R China
2.E China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China

Recommended Citation:
Zhang, Chun,Jiao, Ning. A Cu-catalyzed practical approach to alpha-ketoesters under air: an efficient aerobic oxidative dehydrogenative coupling of alcohols and a-carbonyl aldehydes[J]. Organic Chemistry Frontiers,2014,1(1):109-112.
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