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学科主题: 药学
题名:
Csp(2)-Csp(2) bond formation via Lewis acid/ammonium salt cocatalyzed tandem addition and oxidative dehydrogenation strategy: alkenylation of indoles with alpha,beta-unsaturated ketones
作者: Xiang, Shi-Kai2; Wu, Guolin1; Zhang, Bo1; Cui, Yuxin1; Jiao, Ning1,3
关键词: Alkenylation ; Indoles ; alpha,beta-Unsaturated ketones ; Tandem reaction ; Lewis acids ; Organocatalyst
刊名: TETRAHEDRON LETTERS
发表日期: 2012-07-18
DOI: 10.1016/j.tetlet.2012.05.053
卷: 53, 期:29, 页:3802-3804
收录类别: SCI ; IC ; CCR
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
关键词[WOS]: C-H FUNCTIONALIZATION ; ASYMMETRIC ENAMINE CATALYSIS ; DIRECT C-2 ARYLATION ; ROOM-TEMPERATURE ; PALLADIUM ; PYRROLES ; ALDEHYDES ; CYCLIZATION ; REGIOSELECTIVITY ; ACIDS
英文摘要:

The alkenylation of indoles with alpha,beta-unsaturated ketones through a tandem addition and oxidative dehydrogenation strategy has been developed. This method provides an alternative approach for C3 alkenylation of indoles with alpha,beta-unsaturated ketones. Using inexpensive and readily available BF3 center dot Et2O and an ammonium salt as the efficient cocatalyst constitutes the attractive advantage of this reaction. (C) 2012 Published by Elsevier Ltd.

语种: 英语
所属项目编号: 2009CB825300 ; 20872003 ; 21172006
项目资助者: National Basic Research Program of China (973 Program) ; National Science Foundation of China ; Peking University
WOS记录号: WOS:000306027700028
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/60036
Appears in Collections:北京大学药学院_期刊论文

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作者单位: 1.Perking Univ, Sch Pharmaceut Sci, Peking Univ, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
2.Sichuan Normal Univ, Coll Chem & Mat Sci, Chengdu 610066, Sichuan, Peoples R China
3.E China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China

Recommended Citation:
Xiang, Shi-Kai,Wu, Guolin,Zhang, Bo,et al. Csp(2)-Csp(2) bond formation via Lewis acid/ammonium salt cocatalyzed tandem addition and oxidative dehydrogenation strategy: alkenylation of indoles with alpha,beta-unsaturated ketones[J]. TETRAHEDRON LETTERS,2012,53(29):3802-3804.
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