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Control of Chemo-, Regio-, and Stereoselectivities in Ligand-Free Pd-Catalyzed Oxidative Heck Reactions of Arylboronic Acids or Alkenylboronate with Allyl Esters
Su, Yijin; Jiao, Ning1
刊名ORGANIC LETTERS
2009-07-16
DOI10.1021/ol9009865
11期:14页:2980-2983
收录类别SCI ; CCR
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]COUPLING REACTIONS ; PALLADIUM(II) CATALYSIS ; BASE-FREE ; ROOM-TEMPERATURE ; CROSS-COUPLINGS ; ARYL CHLORIDES ; BOND FORMATION ; ACETATES ; CARBON ; ARYLATION
英文摘要

A ligand-free Pd-catalyzed highly selective oxidative Heck reaction of organoboronic acids with allyl esters was developed. beta-H elimination is highly chemoselectively controlled, leading to gamma-substituted allyl esters, which is contrary to the traditional Heck-type reactions of allyl esters. Moreover, the regio- and stereoselectivities are also high due to the chelation between O and Pd atoms.

语种英语
WOS记录号WOS:000268138800007
项目编号20702002 ; 20872003 ; 2009CB825300
资助机构Peking University ; National Science Foundation of China ; National Basic Research Program of China
引用统计
被引频次:80[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/60120
专题北京大学药学院
北京大学药学院_天然药物与仿生药物国家重点实验室
作者单位1.Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
2.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
推荐引用方式
GB/T 7714
Su, Yijin,Jiao, Ning. Control of Chemo-, Regio-, and Stereoselectivities in Ligand-Free Pd-Catalyzed Oxidative Heck Reactions of Arylboronic Acids or Alkenylboronate with Allyl Esters[J]. ORGANIC LETTERS,2009,11(14):2980-2983.
APA Su, Yijin,&Jiao, Ning.(2009).Control of Chemo-, Regio-, and Stereoselectivities in Ligand-Free Pd-Catalyzed Oxidative Heck Reactions of Arylboronic Acids or Alkenylboronate with Allyl Esters.ORGANIC LETTERS,11(14),2980-2983.
MLA Su, Yijin,et al."Control of Chemo-, Regio-, and Stereoselectivities in Ligand-Free Pd-Catalyzed Oxidative Heck Reactions of Arylboronic Acids or Alkenylboronate with Allyl Esters".ORGANIC LETTERS 11.14(2009):2980-2983.
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