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学科主题: 药学
题名:
Constituents from the roots of Semiaquilegia adoxoides
作者: Niu Feng; Cui Zheng; Chang Hai-Tao; Jiang Yong; Chen Fa-Kui; Tu Peng-Fei
关键词: Semiaquilegia adoxoide ; Semiaquilegine A ; 3-(4 &prime ; -hydroxyphenyl)-2-propenoic acid ; (4 &prime ; &prime ; -carboxyl)-phenyl ester ; cyano-containing compound
刊名: CHINESE JOURNAL OF CHEMISTRY
发表日期: 2006-12-01
卷: 24, 期:12, 页:1788-1791
收录类别: SCI ; IC
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
关键词[WOS]: CYANOGLUCOSIDES ; DC
英文摘要:

In present literature search, some cyano-containing compounds, which are very rare in plants, from the traditional anticancer herb Tiankuizi were reported. To find more cyano-containing compounds in the important plant Semiaquilegia adoxoides (DC) Makino (Chinese name Tiankuizi), the isolation of the chemical constituents was investigated for advancing the research. Two new compounds, a new alkaloid, 1,2,3,4-tetrahydro-6-hydroxy-1-[(3,4-dihydroxyphenyl)methyl]-7-methoxy-2,2-dimethyl-isoquinolinium, named Semiaquilegine A (1), and a new ester, 3-(4′-hydroxyphenyl)-2-propenoic acid (4"-carboxyl)-phenyl ester (2), and four cyano-containing compounds, (Z)-6 alpha-(beta-D-glucosyloxy)-4 alpha,5 alpha-dihydroxy-2-cyclohexene-Delta(1),alpha-acetonitrile (3), (Z)-6 alpha-(beta-D-glucosyloxy)-4 alpha-hydroxy-2-cyclohexene-Delta(1),alpha-acetonitrile (4), lithospermoside (5), ehretioside B (6), as well as eleven known compounds, were isolated from the roots of Semiaquilegia adoxoides. The structures of new compounds 1 and 2 were elucidated mainly by 1D/2D-NMR techniques. Very unusual cyano-containing compounds 3 and 4 were first isolated from Ranunculaceae family. Hitherto, there were six cyano-containing compounds found in the herb.

语种: 英语
WOS记录号: WOS:000242751000020
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/60252
Appears in Collections:北京大学药学院_期刊论文

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作者单位: 1.Peking Univ, Hlth Sci Ctr, Sch Pharmaceut Sci, Beijing 100083, Peoples R China
2.Shenyang Pharmaceut Univ, Dept Pharmacognosy, Sch Tradit Chinese Med, Shenyang 110016, Peoples R China

Recommended Citation:
Niu Feng,Cui Zheng,Chang Hai-Tao,et al. Constituents from the roots of Semiaquilegia adoxoides[J]. CHINESE JOURNAL OF CHEMISTRY,2006,24(12):1788-1791.
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