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学科主题: 药学
题名:
Highly stereoselective synthesis of a seven-membered carbasugar via triisobutylaluminium promoted Claisen rearrangement
作者: Jia, C; Zhang, YM; Zhang, LH
刊名: TETRAHEDRON-ASYMMETRY
发表日期: 2003-08-01
DOI: 10.1016/s0957-4166(03)00490-7
卷: 14, 期:15, 页:2195-2199
收录类别: SCI ; IC ; CCR
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Inorganic & Nuclear ; Chemistry, Organic ; Chemistry, Physical
研究领域[WOS]: Chemistry
关键词[WOS]: ALLYL VINYL ETHERS ; ENANTIOSELECTIVE SYNTHESIS ; CARBOCYCLIC NUCLEOSIDES ; ASYMMETRIC-SYNTHESIS ; ENOL ETHERS ; CARBAPENTOFURANOSES ; DERIVATIVES ; ANALOGS ; ACID
英文摘要:

2-Methylene-5-vinyl-tetrahydrofuran derivative 6 was obtained from alpha-D-glucose. Treatment of 6 with triisobutylaluminium (TIBAL) induced Claisen expansion reaction to give the seven-membered carbasugar derivative 7, which represents a new type of chiral building blocks. The rearrangement reaction has been proved to be highly stereoselective. (C) 2003 Elsevier Ltd. All rights reserved.

语种: 英语
WOS记录号: WOS:000184619100011
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/60899
Appears in Collections:北京大学药学院_期刊论文

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作者单位: 1.Peking Univ, Sch Pharmaceut Sci, Natl Res Lab Nat & Biomimet Drugs, Beijing 100083, Peoples R China
2.Ecole Normale Super, Dept Chim, CNRS, UMR 8642, F-75231 Paris 05, France

Recommended Citation:
Jia, C,Zhang, YM,Zhang, LH. Highly stereoselective synthesis of a seven-membered carbasugar via triisobutylaluminium promoted Claisen rearrangement[J]. TETRAHEDRON-ASYMMETRY,2003,14(15):2195-2199.
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