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Highly stereoselective synthesis of a seven-membered carbasugar via triisobutylaluminium promoted Claisen rearrangement
Jia, C; Zhang, YM; Zhang, LH
刊名TETRAHEDRON-ASYMMETRY
2003-08-01
DOI10.1016/s0957-4166(03)00490-7
14期:15页:2195-2199
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Inorganic & Nuclear ; Chemistry, Organic ; Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]ALLYL VINYL ETHERS ; ENANTIOSELECTIVE SYNTHESIS ; CARBOCYCLIC NUCLEOSIDES ; ASYMMETRIC-SYNTHESIS ; ENOL ETHERS ; CARBAPENTOFURANOSES ; DERIVATIVES ; ANALOGS ; ACID
英文摘要

2-Methylene-5-vinyl-tetrahydrofuran derivative 6 was obtained from alpha-D-glucose. Treatment of 6 with triisobutylaluminium (TIBAL) induced Claisen expansion reaction to give the seven-membered carbasugar derivative 7, which represents a new type of chiral building blocks. The rearrangement reaction has been proved to be highly stereoselective. (C) 2003 Elsevier Ltd. All rights reserved.

语种英语
WOS记录号WOS:000184619100011
引用统计
被引频次:10[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/60899
专题北京大学药学院
作者单位1.Peking Univ, Sch Pharmaceut Sci, Natl Res Lab Nat & Biomimet Drugs, Beijing 100083, Peoples R China
2.Ecole Normale Super, Dept Chim, CNRS, UMR 8642, F-75231 Paris 05, France
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GB/T 7714
Jia, C,Zhang, YM,Zhang, LH. Highly stereoselective synthesis of a seven-membered carbasugar via triisobutylaluminium promoted Claisen rearrangement[J]. TETRAHEDRON-ASYMMETRY,2003,14(15):2195-2199.
APA Jia, C,Zhang, YM,&Zhang, LH.(2003).Highly stereoselective synthesis of a seven-membered carbasugar via triisobutylaluminium promoted Claisen rearrangement.TETRAHEDRON-ASYMMETRY,14(15),2195-2199.
MLA Jia, C,et al."Highly stereoselective synthesis of a seven-membered carbasugar via triisobutylaluminium promoted Claisen rearrangement".TETRAHEDRON-ASYMMETRY 14.15(2003):2195-2199.
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