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Metal 2-hydroxy-1-naphthaldehyde thiosemicarbazone (Me-HNT) complexes - A new kind of biomimic enzyme catalyst
Du, M; Liang, FZ; Tang, B; Luo, YJ; Shen, HX; Teng, B; Liu, Y
关键词biomimic enzyme catalytic activity metal 2-hydroxy-1-naphthaldehyde thiosemicarbazone complexes spectrophotometry
刊名CHINESE CHEMICAL LETTERS
2000
11期:1页:23-26
收录类别SCI
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]PEROXIDASE-LIKE METALLOPORPHYRINS ; HYDROGEN-PEROXIDE
英文摘要

Metal (Me=Fe(III), Mo(VI), Mn(II), Co(II), Ni(II), Zn(II) and Cu(II)) 2-hydroxy-1-naphthaldehyde thiosemicarbazone complexes (MeHNT) were synthesized and used as mimic-enzyme catalysts to mimic the active group of horseradish peroxidase (HRP). The results showed that Fe-HNT, Mo-HNT are effective catalysts, which have similar catalytic activity as HRP. The sequence of catalytic activities of tested biomimic peroxidas is Mo-HNT > Fe-HNT > Zn-HNT > Ni-HNT > Mn-HNT. Among them, Fe-HNT is used as a mimic-enzyme catalyst in determination of ascorbic acid and glucose by coupling the catalytic reaction of glucose oxidase.

语种英语
WOS记录号WOS:000085088700010
引用统计
被引频次:7[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/61264
专题北京大学药学院
作者单位1.Beijing Med Univ, Sch Pharmaceut Sci, Beijing 100083, Peoples R China
2.Shandong Normal Univ, Dept Chem, Jinan 250014, Peoples R China
3.Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
4.Shandong Blood Ctr, Jinan 250014, Peoples R China
推荐引用方式
GB/T 7714
Du, M,Liang, FZ,Tang, B,et al. Metal 2-hydroxy-1-naphthaldehyde thiosemicarbazone (Me-HNT) complexes - A new kind of biomimic enzyme catalyst[J]. CHINESE CHEMICAL LETTERS,2000,11(1):23-26.
APA Du, M.,Liang, FZ.,Tang, B.,Luo, YJ.,Shen, HX.,...&Liu, Y.(2000).Metal 2-hydroxy-1-naphthaldehyde thiosemicarbazone (Me-HNT) complexes - A new kind of biomimic enzyme catalyst.CHINESE CHEMICAL LETTERS,11(1),23-26.
MLA Du, M,et al."Metal 2-hydroxy-1-naphthaldehyde thiosemicarbazone (Me-HNT) complexes - A new kind of biomimic enzyme catalyst".CHINESE CHEMICAL LETTERS 11.1(2000):23-26.
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