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Silicon Powder: The First Nonmetal Elemental Catalyst for Aminobromination of Olefins with TsNH2 and NBS
Wei, Jun-Fa1; Chen, Zhan-Guo1; Lei, Wei1; Zhang, Li-Hui1; Wang, Ming-Zheng1; Shi, Xian-Ying1; Li, Run-Tao2
刊名ORGANIC LETTERS
2009-09-17
DOI10.1021/ol9015833
11期:18页:4216-4219
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]ELECTROPHILIC DIAMINATION ; STEREOSELECTIVE AMINOHALOGENATION ; ALPHA,BETA-UNSATURATED KETONES ; CINNAMIC ESTERS ; BROMINE SOURCES ; HALOGEN SOURCES ; ALKENES ; NITROGEN ; AMINOCHLORINATION ; COMBINATION
英文摘要

Silicon powder was found, for the first time, to be an efficient alternative to transition metal catalysts for aminobromination of alpha,beta-unsaturated carbonyl compounds and simple olefins with p-toluenesulfonamide (4-TsNH2) and NBS, affording the aminobrominated products in high yields and regio- and stereoselectivity. The high reactivity of electron-rich substrates reveals that the reaction has the electrophilic addition feature.

语种英语
WOS记录号WOS:000269670700048
Citation statistics
Cited Times:37[WOS]   [WOS Record]     [Related Records in WOS]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/61328
Collection北京大学药学院
北京大学药学院_化学生物学系
作者单位1.Shaanxi Normal Univ, Sch Chem & Mat Sci, Shaanxi Xian 710062, Peoples R China
2.Peking Univ, Sch Pharmaceut Sci, Beijing 100083, Peoples R China
Recommended Citation
GB/T 7714
Wei, Jun-Fa,Chen, Zhan-Guo,Lei, Wei,et al. Silicon Powder: The First Nonmetal Elemental Catalyst for Aminobromination of Olefins with TsNH2 and NBS[J]. ORGANIC LETTERS,2009,11(18):4216-4219.
APA Wei, Jun-Fa.,Chen, Zhan-Guo.,Lei, Wei.,Zhang, Li-Hui.,Wang, Ming-Zheng.,...&Li, Run-Tao.(2009).Silicon Powder: The First Nonmetal Elemental Catalyst for Aminobromination of Olefins with TsNH2 and NBS.ORGANIC LETTERS,11(18),4216-4219.
MLA Wei, Jun-Fa,et al."Silicon Powder: The First Nonmetal Elemental Catalyst for Aminobromination of Olefins with TsNH2 and NBS".ORGANIC LETTERS 11.18(2009):4216-4219.
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