IR@PKUHSC  > 北京大学药学院
学科主题药学
Sialylation reactions with N,N-acetyl, benzoyl-O-perbenzoyl-protected sialyl donor
Wang, Yue; Ye, Xin-Shan1
关键词Sialylation Glycosylation Stereoselectivity Carbohydrate Synthetic method
刊名TETRAHEDRON LETTERS
2009-07-08
DOI10.1016/j.tetlet.2009.04.034
50期:27页:3823-3826
收录类别SCI ; IC
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Organic
资助者National Natural Science Foundation of China ; Ministry of Science and Technology of China ; National Natural Science Foundation of China ; Ministry of Science and Technology of China
研究领域[WOS]Chemistry
关键词[WOS]ACID DONORS ; GLYCOSIDES ; STRATEGY
英文摘要

A new sialyl donor, N,N-acetyl, benzoyl-O-perbenzoyl-protected p-toluenethiosialoside, was synthesized and its sialylation reaction was investigated. This reaction proceeded in dichloromethane and beta anomeric selectivity was achieved when NIS-TfOH was used as promoter. This method may be employed to construct the unnatural beta-linked sialosides. (C) 2009 Elsevier Ltd. All rights reserved.

语种英语
资助者National Natural Science Foundation of China ; Ministry of Science and Technology of China ; National Natural Science Foundation of China ; Ministry of Science and Technology of China
WOS记录号WOS:000266890000023
Citation statistics
Cited Times:8[WOS]   [WOS Record]     [Related Records in WOS]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/61843
Collection北京大学药学院
作者单位1.Peking Univ, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
2.Peking Univ, Sch Pharmaceut Sci, Beijing 100191, Peoples R China
Recommended Citation
GB/T 7714
Wang, Yue,Ye, Xin-Shan. Sialylation reactions with N,N-acetyl, benzoyl-O-perbenzoyl-protected sialyl donor[J]. TETRAHEDRON LETTERS,2009,50(27):3823-3826.
APA Wang, Yue,&Ye, Xin-Shan.(2009).Sialylation reactions with N,N-acetyl, benzoyl-O-perbenzoyl-protected sialyl donor.TETRAHEDRON LETTERS,50(27),3823-3826.
MLA Wang, Yue,et al."Sialylation reactions with N,N-acetyl, benzoyl-O-perbenzoyl-protected sialyl donor".TETRAHEDRON LETTERS 50.27(2009):3823-3826.
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