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学科主题: 药学
题名:
Ceric Ammonium Nitrate (CAN) Catalyzed Modification of Ketones via Two C-C Bond Cleavages with the Retention of the Oxo-Group
作者: Feng, Peng1; Sun, Xiang1; Su, Yijin2; Li, Xinyao1; Zhang, Li-He1; Shi, Xiaodong2; Jiao, Ning1,3
刊名: ORGANIC LETTERS
发表日期: 2014-06-20
DOI: 10.1021/ol5014476
卷: 16, 期:12, 页:3388-3391
收录类别: SCI ; IC ; CCR
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
关键词[WOS]: CARBON-HYDROGEN BONDS ; H ACTIVATION ; AEROBIC OXYGENATION ; AMINYL RADICALS ; SODIUM-AZIDE ; ALDEHYDES ; RHODIUM ; ARYLATION ; CERIUM(IV) ; EFFICIENT
英文摘要:

A simple ceric ammonium nitrate (CAN) catalyzed functionalization of ketones through double C-C bond cleavage strategy has been disclosed. This reaction provides a mild, practical method toward carbamoyl azides, which are versatile intermediates and building blocks in organic synthesis. Based on relevant mechanistic studies, a unique and plausible C-C bond and N-O bond cleavage process is proposed, where the oxyamination intermediate plays an important role in this reaction.

语种: 英语
所属项目编号: 21325206 ; 21172006 ; 20120001110013
项目资助者: National Science Foundation of China ; National Young Top-notch Talent Support Program ; Ph.D. Programs Foundation of the Ministry of Education of China
WOS记录号: WOS:000337869800055
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/62059
Appears in Collections:北京大学药学院_期刊论文

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作者单位: 1.Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
2.W Virginia Univ, C Eugene Bennett Dept Chem, Morgantown, WV 26506 USA
3.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

Recommended Citation:
Feng, Peng,Sun, Xiang,Su, Yijin,et al. Ceric Ammonium Nitrate (CAN) Catalyzed Modification of Ketones via Two C-C Bond Cleavages with the Retention of the Oxo-Group[J]. ORGANIC LETTERS,2014,16(12):3388-3391.
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