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Metal-Free, NHPI Catalyzed Oxidative Cleavage of C-C Double Bond Using Molecular Oxygen as Oxidant
Lin, Riyuan1; Chen, Feng1; Jiao, Ning1,2
刊名ORGANIC LETTERS
2012-08-17
DOI10.1021/ol3018215
14期:16页:4158-4161
收录类别SCI ; CCR
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]M-CHLOROPERBENZOIC ACID ; CARBON DOUBLE-BONDS ; N-HYDROXYPHTHALIMIDE ; AEROBIC OXIDATION ; DIOXYGEN ACTIVATION ; SELECTIVE OXIDATION ; CIS-DIHYDROXYLATION ; ORGANIC-CHEMICALS ; HYDROGEN-PEROXIDE ; ELECTRON-TRANSFER
英文摘要

A metal-free N-hydroxyphthalimide (NHPI) catalyzed aerobic oxidative cleavage of olefins has been developed. Molecular oxygen is used as the oxidant and reagent for this oxygenation reaction. This methodology has prevented the use of toxic metals or overstoichiometric amounts of traditional oxidants, showing good economical and environmental advantages. Based on the experimental observations, a plausible mechanism is proposed.

语种英语
WOS记录号WOS:000307526900032
项目编号2009CB825300 ; 21172006
资助机构National Basic Research Program of China (973 Program) ; National Science Foundation of China ; Peking University
引用统计
被引频次:99[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/62256
专题北京大学药学院
北京大学药学院_天然药物与仿生药物国家重点实验室
作者单位1.Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
2.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
推荐引用方式
GB/T 7714
Lin, Riyuan,Chen, Feng,Jiao, Ning. Metal-Free, NHPI Catalyzed Oxidative Cleavage of C-C Double Bond Using Molecular Oxygen as Oxidant[J]. ORGANIC LETTERS,2012,14(16):4158-4161.
APA Lin, Riyuan,Chen, Feng,&Jiao, Ning.(2012).Metal-Free, NHPI Catalyzed Oxidative Cleavage of C-C Double Bond Using Molecular Oxygen as Oxidant.ORGANIC LETTERS,14(16),4158-4161.
MLA Lin, Riyuan,et al."Metal-Free, NHPI Catalyzed Oxidative Cleavage of C-C Double Bond Using Molecular Oxygen as Oxidant".ORGANIC LETTERS 14.16(2012):4158-4161.
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