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学科主题: 药学
题名:
Metal-Free, NHPI Catalyzed Oxidative Cleavage of C-C Double Bond Using Molecular Oxygen as Oxidant
作者: Lin, Riyuan1; Chen, Feng1; Jiao, Ning1,2
刊名: ORGANIC LETTERS
发表日期: 2012-08-17
DOI: 10.1021/ol3018215
卷: 14, 期:16, 页:4158-4161
收录类别: SCI ; CCR
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
关键词[WOS]: M-CHLOROPERBENZOIC ACID ; CARBON DOUBLE-BONDS ; N-HYDROXYPHTHALIMIDE ; AEROBIC OXIDATION ; DIOXYGEN ACTIVATION ; SELECTIVE OXIDATION ; CIS-DIHYDROXYLATION ; ORGANIC-CHEMICALS ; HYDROGEN-PEROXIDE ; ELECTRON-TRANSFER
英文摘要:

A metal-free N-hydroxyphthalimide (NHPI) catalyzed aerobic oxidative cleavage of olefins has been developed. Molecular oxygen is used as the oxidant and reagent for this oxygenation reaction. This methodology has prevented the use of toxic metals or overstoichiometric amounts of traditional oxidants, showing good economical and environmental advantages. Based on the experimental observations, a plausible mechanism is proposed.

语种: 英语
所属项目编号: 2009CB825300 ; 21172006
项目资助者: National Basic Research Program of China (973 Program) ; National Science Foundation of China ; Peking University
WOS记录号: WOS:000307526900032
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/62256
Appears in Collections:北京大学药学院_期刊论文

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作者单位: 1.Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
2.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

Recommended Citation:
Lin, Riyuan,Chen, Feng,Jiao, Ning. Metal-Free, NHPI Catalyzed Oxidative Cleavage of C-C Double Bond Using Molecular Oxygen as Oxidant[J]. ORGANIC LETTERS,2012,14(16):4158-4161.
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