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学科主题: 药学
题名:
Metal-free nitro-carbocyclization of activated alkenes: a direct approach to synthesize oxindoles by cascade C-N and C-C bond formation
作者: Shen, Tao1; Yuan, Yizhi1; Jiao, Ning1,2
刊名: CHEMICAL COMMUNICATIONS
发表日期: 2014
DOI: 10.1039/c3cc47336h
卷: 50, 期:5, 页:554-556
收录类别: SCI ; IC ; CCR
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
关键词[WOS]: TERT-BUTYL NITRITE ; AQUEOUS-SOLUTION ; ALKYL NITRITES ; H ACTIVATION ; SIDE-CHAIN ; NITRATION ; ACID ; AMINATION ; CHEMISTRY ; KINETICS
英文摘要:

A novel and direct metal-free nitro-carbocyclization of activated alkenes leading to valuable nitro-containing oxindoles via cascade C-N and C-C bond formation has been developed. The mechanistic study indicates that the initial NO and NO2 radical addition and the following C-H functionalization processes are involved in this transformation.

语种: 英语
所属项目编号: 21172006 ; 20120001110013
项目资助者: National Science Foundation of China ; Ministry of Education of China
WOS记录号: WOS:000328650000015
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/62540
Appears in Collections:北京大学药学院_期刊论文

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作者单位: 1.Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
2.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

Recommended Citation:
Shen, Tao,Yuan, Yizhi,Jiao, Ning. Metal-free nitro-carbocyclization of activated alkenes: a direct approach to synthesize oxindoles by cascade C-N and C-C bond formation[J]. CHEMICAL COMMUNICATIONS,2014,50(5):554-556.
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