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学科主题: 药学
题名:
Diasteroselective cyclizations with enantiopure malonaldehyde monocycloacetals
作者: Bi, LR; Zhao, M; Wang, C; Peng, SQ; Winterfeldt, E
刊名: JOURNAL OF ORGANIC CHEMISTRY
发表日期: 2002-01-11
DOI: 10.1021/jo0057351
卷: 67, 期:1, 页:22-26
收录类别: SCI ; IC ; CCR
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
关键词[WOS]: MONOACETALS
英文摘要:

The synthesis of a series of enantiopure malonaldehyde monocycloacetals is described. Treatment of 8b with L-tryptophan methyl ester, 5-methoxytryptamine, and tryptamine, respectively, in the Pictet-Spengler condensation gave the corresponding enantiomerically pure key precursors 1-3 and 17-21 in only two steps. Using a chiral amino-diol successfully realized the kinetic resolution of racemic carbolines 23 and 24.

语种: 英语
WOS记录号: WOS:000173151200005
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/62949
Appears in Collections:北京大学药学院_期刊论文

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作者单位: 1.Univ Hannover, Inst Organ Chem, D-30167 Hannover, Germany
2.Peking Univ, Coll Pharmaceut Sci, Beijing 100083, Peoples R China

Recommended Citation:
Bi, LR,Zhao, M,Wang, C,et al. Diasteroselective cyclizations with enantiopure malonaldehyde monocycloacetals[J]. JOURNAL OF ORGANIC CHEMISTRY,2002,67(1):22-26.
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