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Hypervalent Iodine Mediated para-Selective Fluorination of Anilides
Tian, Tian; Zhong, Wen-He; Meng, Shuai; Meng, Xiang-Bao; Li, Zhong-Jun
刊名JOURNAL OF ORGANIC CHEMISTRY
2013-01-18
DOI10.1021/jo302099d
78期:2页:728-732
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]METAL-FREE ; REDUCTIVE ELIMINATION ; DIARYLIODONIUM-SALTS ; FUNCTIONALIZED ARYL ; PALLADIUM FLUORIDE ; ELEMENTAL FLUORINE ; BOND FORMATION ; COMPLEXES ; DIACETOXYLATION ; SELECTFLUOR
英文摘要

A metal-free method for the direct regioselective fluorination of anilides has been developed. In the presence of bis(tert-butylcarbonyloxy)iodobenzene (PhI(OPiv)(2)) and hydrogen fluoride-pyridine, the para-fluorination products of anilides were obtained in moderate to good yields. Because of its operational safety and the use of readily available reagents, this new procedure provides facile access to a variety of para-fluorinated anilides.

语种英语
WOS记录号WOS:000314008700053
项目编号2012CB822100 ; 20972012
资助机构National Basic Research Program of China ; National Natural Science Foundation of China
引用统计
被引频次:33[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/63286
专题北京大学药学院
北京大学药学院_化学生物学系
北京大学口腔医学院_护理部
作者单位Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
推荐引用方式
GB/T 7714
Tian, Tian,Zhong, Wen-He,Meng, Shuai,et al. Hypervalent Iodine Mediated para-Selective Fluorination of Anilides[J]. JOURNAL OF ORGANIC CHEMISTRY,2013,78(2):728-732.
APA Tian, Tian,Zhong, Wen-He,Meng, Shuai,Meng, Xiang-Bao,&Li, Zhong-Jun.(2013).Hypervalent Iodine Mediated para-Selective Fluorination of Anilides.JOURNAL OF ORGANIC CHEMISTRY,78(2),728-732.
MLA Tian, Tian,et al."Hypervalent Iodine Mediated para-Selective Fluorination of Anilides".JOURNAL OF ORGANIC CHEMISTRY 78.2(2013):728-732.
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