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Conformational effect on the keto-enol tautomerism of alpha-carbonylcyclododecanones
Yang, XL; Wang, MA; Liang, XM; Wang, XF; You, TB; Wang, DQ
关键词keto-enol tautomerism alpha-carbonylcyclododecanone conformational effect
刊名CHINESE JOURNAL OF ORGANIC CHEMISTRY
2005-10-01
25期:10页:1279-1282
收录类别SCI
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]CYCLODODECANONES
英文摘要

The keto-enol tautomerism of alpha-carbonylcyclododecanones has been studied by means of H-1 NMR technology. The result shows that the effects of substituent, temperature and solvent on the tautomerism agreed with the known rules, while their enol contents were much lower than those of the corresponding alpha-carbonylcyclohexanones, which is illustrated reasonably by the conformational effect.

语种中文
WOS记录号WOS:000232416200020
引用统计
被引频次:2[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/63342
专题北京大学药学院
作者单位1.China Agr Univ, Dept Appl Chem, Beijing 100094, Peoples R China
2.Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China
3.Peking Univ, Sch Pharmaceut Sci, Beijing 100083, Peoples R China
推荐引用方式
GB/T 7714
Yang, XL,Wang, MA,Liang, XM,et al. Conformational effect on the keto-enol tautomerism of alpha-carbonylcyclododecanones[J]. CHINESE JOURNAL OF ORGANIC CHEMISTRY,2005,25(10):1279-1282.
APA Yang, XL,Wang, MA,Liang, XM,Wang, XF,You, TB,&Wang, DQ.(2005).Conformational effect on the keto-enol tautomerism of alpha-carbonylcyclododecanones.CHINESE JOURNAL OF ORGANIC CHEMISTRY,25(10),1279-1282.
MLA Yang, XL,et al."Conformational effect on the keto-enol tautomerism of alpha-carbonylcyclododecanones".CHINESE JOURNAL OF ORGANIC CHEMISTRY 25.10(2005):1279-1282.
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