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学科主题: 药学
题名:
Total synthesis of crisamicin A
作者: Li, Zhengtao; Gao, Yingxiang; Tang, Yefeng; Dai, Mingji; Wang, Guoxin; Wang, Zhigang1; Yang, Zhen
刊名: ORGANIC LETTERS
发表日期: 2008-07-17
DOI: 10.1021/ol800977n
卷: 10, 期:14, 页:3017-3020
收录类别: SCI ; IC ; CCR
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
关键词[WOS]: CROSS-COUPLING REACTIONS ; DIELS-ALDER REACTIONS ; PAUSON-KHAND REACTION ; INTRAMOLECULAR AMINOCARBONYLATION ; CARBONYLATIVE ANNULATION ; ABSOLUTE-CONFIGURATION ; EFFICIENT SYNTHESIS ; PALLADIUM-THIOUREA ; FRENOLICIN-B ; ARYL HALIDES
英文摘要:

Stereoselective total synthesis of natural product crisamicin A (1) was accomplished for the first time via the Pd/TMTU-catalyzed alkoxycarbonylative annulation to generate a unique cis-pyran-fused lactone, an intermolecular Diels-Alder reaction to construct the pyranonaphthoquinone unit, and a novel Pd-thiourea pincer complex-catalyzed homocoupling of functionalized naphthoquinones.

语种: 英语
WOS记录号: WOS:000257629200026
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/63531
Appears in Collections:北京大学药学院_期刊论文

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作者单位: 1.Peking Univ, Minist Educ, Shenzhen Grad Sch, Key Lab Bioorgan Chem & Mol Engn,Lab Chem Genom, Beijing 100871, Peoples R China
2.Peking Univ, BNLMS, Coll Chem, Beijing 100871, Peoples R China
3.Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100871, Peoples R China

Recommended Citation:
Li, Zhengtao,Gao, Yingxiang,Tang, Yefeng,et al. Total synthesis of crisamicin A[J]. ORGANIC LETTERS,2008,10(14):3017-3020.
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